Laboratory of Multiscale Studies in Building Physics, Empa, Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, 8600 Dübendorf, Switzerland; Laboratory for Biomimetic Membranes and Textiles, Empa, Swiss Federal Laboratories for Materials Science and Technology, Lerchenfeldstrasse 5, 9014 St. Gallen, Switzerland; Chair of Building Physics, Swiss Federal Institute of Technology Zürich (ETHZ), Stefano-Franscini-Platz 5, 8093 Zürich, Switzerland.
Swiss Light Source, Paul Scherrer Institut, 5232 Villigen PSI, Switzerland.
J Colloid Interface Sci. 2022 Nov 15;626:416-425. doi: 10.1016/j.jcis.2022.06.103. Epub 2022 Jun 30.
Wicking flow in the wale direction of knit fabrics is slowed by capillary pressure minima during the transition at yarn contacts. The characteristic pore structure of yarns leads to an unfavorable free energy evolution and is the cause of these minima.
Time-resolved synchrotron tomographic microscopy is employed to study the evolution of water configuration during wicking flow in interlacing yarns. Dynamic pore network modeling is used based on the obtained image data and distributions of delay times for pore intrusion. Good agreement is observed by comparison to the experimental data.
Yarn-to-yarn transition is found to coincide with slow water advance in a thin interface zone at the yarn contact. The pore spaces of the two yarns merge within this interface zone and provide a transition path. A deep capillary pressure minimum occurs while water passes through the center of the interface zone, effectively delaying the wicking flow. A pore network model considering pore intrusion delay times is expanded to include inter-yarn wicking and reproduce the observed wicking dynamics.
在纱线接触处的过渡过程中,针织物的经向芯吸流动会受到毛细压力最小值的阻碍。纱线的特征孔隙结构导致不利的自由能演化,这是产生这些最小值的原因。
采用时间分辨同步加速器断层显微镜研究交织纱线芯吸流动过程中水分结构的演变。基于获得的图像数据和孔侵入延迟时间分布,采用动态孔隙网络建模。通过与实验数据的比较,观察到了很好的一致性。
发现纱线到纱线的过渡与纱线接触处薄界面区的水缓慢推进相吻合。在这个界面区内,两根纱线的孔隙空间合并,提供了一个过渡路径。当水通过界面区中心时,会出现一个很深的毛细压力最小值,有效地延迟了芯吸流动。一个考虑到孔侵入延迟时间的孔隙网络模型被扩展到包括纱线间芯吸,并再现了观察到的芯吸动力学。