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无铅铋铁氧体基压电材料：争议问题与当前研究现状综述

Lead-Free BiFeO-Based Piezoelectrics: A Review of Controversial Issues and Current Research State.

作者信息

Kim Sangwook, Nam Hyunwook, Calisir Ilkan

机构信息

Graduate School of Advanced Science and Engineering, Hiroshima University, Higashihiroshima 739-8526, Hiroshima, Japan.

Graduate Faculty of Interdisciplinary Research, University of Yamanashi, Kofu 400-8510, Yamanashi, Japan.

出版信息

Materials (Basel). 2022 Jun 21;15(13):4388. doi: 10.3390/ma15134388.

DOI:10.3390/ma15134388
PMID:35806509
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9267473/
Abstract

Lead-free electroceramics represent an emerging area of research that has the potential to enable new green advances in electronics. Research has mainly focused on the development of new piezoelectric materials for replacing lead containing oxides exhibiting superior electromechanical behavior. Lead-free BiFeO-based materials are not only the promising candidates to replace lead-based materials but also show intriguing properties which may inspire innovative material design for the next generation of lead-free piezoceramics. This review aims to highlight the current state of research and overlooked aspects in lead-free BiFeO-based ceramics, which could be insightful in elucidating certain controversial issues. Current strategies to reduce high conductivity, influence of chemical heterogeneity on both functional properties and crystal structure, effective heat treatment procedures, and the role of pseudo-cubic structures on the enhancement of piezoelectric properties are subjects of highlighted within this review as they have a significant impact on the quality of BiFeO-based lead-free piezoelectrics (but are often disregarded).

摘要

无铅电子陶瓷是一个新兴的研究领域，有望推动电子领域实现新的绿色发展。研究主要集中在开发新型压电材料，以取代具有优异机电性能的含铅氧化物。无铅铋铁氧体基材料不仅是替代铅基材料的有前途的候选材料，而且还展现出引人入胜的特性，这可能会激发下一代无铅压电陶瓷的创新材料设计。本综述旨在突出无铅铋铁氧体基陶瓷的研究现状和被忽视的方面，这对于阐明某些有争议的问题可能具有启发性。降低高电导率的当前策略、化学不均匀性对功能特性和晶体结构的影响、有效的热处理程序以及伪立方结构对压电性能增强的作用，在本综述中均作为重点内容，因为它们对铋铁氧体基无铅压电材料的质量有重大影响（但常常被忽视）。

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