Department of Chemistry and Chemical Technologies, University of Calabria, 87036 Rende, Italy.
Department of Pharmacy, Health and Nutritional Sciences, University of Calabria, 87036 Rende, Italy.
Molecules. 2022 Jun 23;27(13):4044. doi: 10.3390/molecules27134044.
Water decontamination is an important challenge resulting from the incorrect disposal of heavy metal waste into the environment. Among the different available techniques (e.g., filtration, coagulation, precipitation, and ion-exchange), adsorption is considered the cheapest and most effective procedure for the removal of water pollutants. In the last years, several materials have been tested for the removal of heavy metals from water, including metal-organic frameworks (MOFs), single-walled carbon nanotubes (SWCNTs), and graphene oxide (GO). Nevertheless, their powder consistency, which makes the recovery and reuse after adsorption difficult, is the main drawback for these materials. More recently, SWCNT buckypapers (SWCNT BPs) have been proposed as self-standing porous membranes for filtration and adsorption processes. In this paper, the adsorption capacity and selectivity of Pb (both from neat solutions and in the presence of other interferents) by SWCNT BPs were evaluated as a function of the increasing amount of GO used in their preparation (GO-SWCNT buckypapers). The highest adsorption capacity, 479 ± 25 mg g, achieved for GO-SWCNT buckypapers with 75 wt.% of graphene oxide confirmed the effective application of such materials for cheap and fast water decontamination from lead.
水的净化是一个重大的挑战,起因是重金属废物的不当处理被排放到环境中。在现有的不同技术中(例如过滤、凝结、沉淀和离子交换),吸附被认为是去除水中污染物最廉价和最有效的方法。在过去的几年中,已经有多种材料被测试用于从水中去除重金属,包括金属有机骨架(MOFs)、单壁碳纳米管(SWCNTs)和氧化石墨烯(GO)。然而,这些材料的主要缺点是其粉末状的一致性,这使得吸附后的回收和再利用变得困难。最近,SWCNT 叠层纸(SWCNT BPs)已被提议作为自支撑多孔膜,用于过滤和吸附过程。在本文中,SWCNT BPs 对 Pb 的吸附容量和选择性(无论是在纯溶液中还是在存在其他干扰物的情况下)被评估为其制备过程中使用的 GO 量增加的函数(GO-SWCNT 叠层纸)。对于 GO 含量为 75wt.%的 GO-SWCNT 叠层纸,其达到的最高吸附容量为 479±25mg g,证实了这些材料可有效应用于廉价、快速地净化水中的铅。