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基于复合电极材料的微纳储能器件

Micro/Nano Energy Storage Devices Based on Composite Electrode Materials.

作者信息

Niu Yanqi, Shang Deyong, Li Zhanping

机构信息

School of Mechanical, Electronic & Information Engineering, China University of Mining and Technology (Beijing), Beijing 100083, China.

Institute of Intelligent Mining & Robotics, China University of Mining and Technology (Beijing), Beijing 100083, China.

出版信息

Nanomaterials (Basel). 2022 Jun 27;12(13):2202. doi: 10.3390/nano12132202.

Abstract

It is vital to improve the electrochemical performance of negative materials for energy storage devices. The synergistic effect between the composites can improve the total performance. In this work, we prepare α-FeO@MnO on carbon cloth through hydrothermal strategies and subsequent electrochemical deposition. The α-FeO@MnO hybrid structure benefits electron transfer efficiency and avoids the rapid decay of capacitance caused by volume expansion. The specific capacitance of the as-obtained product is 615 mF cm at 2 mA cm. Moreover, a flexible supercapacitor presents an energy density of 0.102 mWh cm at 4.2 W cm. Bending tests of the device at different angles show excellent mechanical flexibility.

摘要

提高储能设备负极材料的电化学性能至关重要。复合材料之间的协同效应可以提高整体性能。在这项工作中,我们通过水热法和随后的电化学沉积在碳布上制备了α-FeO@MnO。α-FeO@MnO混合结构有利于电子转移效率,并避免了因体积膨胀导致的电容快速衰减。所制备产品在2 mA cm时的比电容为615 mF cm。此外,一种柔性超级电容器在4.2 W cm时的能量密度为0.102 mWh cm。该器件在不同角度下的弯曲测试显示出优异的机械柔韧性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a670/9268354/d58eb105eabd/nanomaterials-12-02202-g001.jpg

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