Zhang Jindong, Bi Ran, Jiang Shengda, Wen Zihao, Luo Chuyang, Yao Jianan, Liu Gang, Chen Chunhai, Wang Ming
Center for Advanced Low-Dimension Materials, State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China.
Shanghai High Performance Fibers and Composites Center (Province-Ministry Joint), Center for Civil Aviation Composites, Donghua University, Shanghai 201620, China.
Polymers (Basel). 2022 Jun 30;14(13):2676. doi: 10.3390/polym14132676.
The ablation mechanism and performance of carbon fiber (CF)-reinforced poly aryl ether ketone (PAEK) thermoplastic composites were studied in this paper. The results show that the ablation damaged area is controlled by the irradiation energy, while the mass loss rate is controlled by the irradiation power density. In the ablation center, the PAEK resin and CFs underwent decomposition and sublimation in an anaerobic environment. In the transition zone, the resin experienced decomposition and remelting in an aerobic environment, and massive char leaves were present in the cross section. In the heat-affected zone, only remelting of the resin was observed. The fusion and decomposition of the resin caused delamination and pores in the composites. Moreover, oxygen appeared crucial to the ablation morphology of CFs. In an aerobic environment, a regular cross section formed, while in an anaerobic environment, a cortex-core structure formed. The cortex-core structure of CF inside the ablation pit was caused by the inhomogeneity of fibers along the radial direction and the residual carbon layer generated by resin decomposition in an anoxic environment. The description of the ablation mechanism presented in this study broadens our understanding of damage evolution in thermoplastic composites subjected to high-energy CW laser irradiation.
本文研究了碳纤维(CF)增强聚芳醚酮(PAEK)热塑性复合材料的烧蚀机理与性能。结果表明,烧蚀损伤面积受辐照能量控制,而质量损失率受辐照功率密度控制。在烧蚀中心,PAEK树脂和CFs在厌氧环境中发生分解和升华。在过渡区,树脂在有氧环境中经历分解和重熔,横截面中存在大量炭化层。在热影响区,仅观察到树脂重熔。树脂的熔融和分解导致复合材料中出现分层和孔隙。此外,氧气对CFs的烧蚀形态至关重要。在有氧环境中形成规则的横截面,而在厌氧环境中形成皮层-芯结构。烧蚀坑内CF的皮层-芯结构是由纤维沿径向的不均匀性以及缺氧环境中树脂分解产生的残余碳层引起的。本研究中对烧蚀机理的描述拓宽了我们对热塑性复合材料在高能连续波激光辐照下损伤演变的理解。