Department of Mechanical Engineering, Bucknell University, Lewisburg, USA.
Environ Sci Pollut Res Int. 2022 Dec;29(59):89449-89468. doi: 10.1007/s11356-022-22032-w. Epub 2022 Jul 19.
Small (< 8 kW) non-road engines are a significant source of pollutants such as particle number (PN) emissions. Many small non-road engines do not have diesel particulate filters (DPFs). They are so designed that air-fuel ratio (AFR) can be adjusted to control visible diesel smoke and particulate matter (PM) resulting from larger accumulation mode particles. However, the effect of AFR variation on smaller nucleation mode nanoparticle emissions is not well understood. Several studies on larger engines have reported a trade-off between smaller and larger particles. In this study, AFR was independently varied over the entire engine map of a naturally aspirated (NA) non-road small diesel engine using forced induction (FI) of externally compressed air. AFR's ranged from 57 to 239 compared to the design range of 23-92 for the engine, including unusually high AFR's at full-load operation, not previously reported for conventional combustion. As expected, larger accumulation mode particles were lowered (up to 15 times) for FI operation. However, the smaller nucleation mode nanoparticles increased up to 15 times. Accumulation mode particles stopped decreasing above an AFR threshold while nucleation particles continuously increased. In-cylinder combustion analysis showed a slightly smaller ignition delay and higher burn rate for FI cases relative to NA operation. Much higher peak cylinder pressures were accompanied by much lower combustion and exhaust gas temperatures (EGT), due to higher in-cylinder mass during FI operation. Peak nucleation mode emissions were shown to be negatively correlated to EGT for all the data, collapsing on a single curve. This is consistent with some other studies reporting increased nucleation mode emissions (and higher accumulation mode particles) with decreased load, lower speed, lower EGR, advanced combustion phasing, and higher injection pressure, all of which reduce EGT. The nucleation-accumulation trade-off has been explained by the 'adsorption hypothesis' by some investigators. In the current work, an alternative/supplemental argument has been made for the possibility that lower cylinder temperatures during the late-burning phase (correlated to lower EGT) phase hampers oxidation of nucleation mode particles and increases nucleation mode emissions.
小型(<8kW)非道路发动机是污染物的重要来源,例如颗粒数(PN)排放。许多小型非道路发动机没有柴油颗粒过滤器(DPF)。它们的设计可以调整空燃比(AFR),以控制可见的柴油烟雾和较大积聚模式颗粒导致的颗粒物(PM)。然而,AFR 变化对较小的成核模式纳米颗粒排放的影响尚不清楚。一些较大发动机的研究报告了较小和较大颗粒之间的权衡。在这项研究中,使用外部压缩空气强制进气(FI)在自然吸气(NA)非道路小型柴油发动机的整个发动机图上独立改变 AFR。与发动机的设计范围(23-92)相比,AFR 范围从 57 到 239,包括在满载运行时异常高的 AFR,这在传统燃烧中以前没有报道过。正如预期的那样,FI 操作降低了较大的积聚模式颗粒(最多降低 15 倍)。然而,较小的成核模式纳米颗粒增加了多达 15 倍。在 AFR 阈值以上,积聚模式颗粒停止减少,而成核颗粒持续增加。与 NA 操作相比,缸内燃烧分析显示 FI 情况下点火延迟略有减小,燃烧和废气温度(EGT)较高。由于 FI 操作期间缸内质量较高,峰值气缸压力高得多,同时燃烧和废气温度(EGT)低得多。对于所有数据,显示出峰值成核模式排放与 EGT 呈负相关,收缩到单个曲线上。这与其他一些研究一致,这些研究报告称,随着负荷、速度、EGR、燃烧相位和喷射压力的降低,成核模式排放增加(以及较大的积聚模式颗粒),所有这些都会降低 EGT。一些研究人员通过“吸附假说”解释了成核-积聚权衡。在当前工作中,提出了一个替代/补充的论点,即燃烧后期(与较低的 EGT 相关)期间较低的气缸温度可能会阻碍成核模式颗粒的氧化,并增加成核模式排放。