Yu Shuang, Ying Jun, Tian Aixiang
College of Chemistry and Materials Engineering, Bohai University, Jinzhou, 121013, P. R. China.
Chempluschem. 2022 Jul;87(7):e202200171. doi: 10.1002/cplu.202200171.
Viologen derived from 4,4'-bipyridine has attracted much attention because of its color changing properties with electron transfer, unique redox stability and structural diversity. These characteristics have led to its successful use in various applications, in particular in color-changing materials. In the past few years, researchers have been working on the syntheses of viologen-based color-changing functional materials, and such materials have been widely used in many fields. In photochromic materials, it is used as anti-counterfeiting material; in thermochromic, it is used as memory storage material, and in electrochromic, it is used as a battery material. This Review discusses the progress of viologen in organic and inorganic discoloration materials in recent years. The syntheses of viologen and its derivatives are summarized, and its application in the field of discoloration materials is introduced.
源自4,4'-联吡啶的紫精因其随电子转移而变色的特性、独特的氧化还原稳定性和结构多样性而备受关注。这些特性使其成功应用于各种领域，特别是在变色材料方面。在过去几年中，研究人员一直致力于基于紫精的变色功能材料的合成，并且这类材料已在许多领域得到广泛应用。在光致变色材料中，它用作防伪材料；在热致变色中，它用作记忆存储材料，而在电致变色中，它用作电池材料。本综述讨论了近年来紫精在有机和无机变色材料方面的进展。总结了紫精及其衍生物的合成，并介绍了其在变色材料领域的应用。
