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通用色基树脂基复合材料:通过准静态和粘弹性行为分析量化老化行为。

Universal Chromatic Resin-Based Composites: Aging Behavior Quantified by Quasi-Static and Viscoelastic Behavior Analysis.

作者信息

Ilie Nicoleta

机构信息

Department of Conservative Dentistry and Periodontology, University Hospital, LMU, Goethestr. 70, 80336 Munich, Germany.

出版信息

Bioengineering (Basel). 2022 Jun 22;9(7):270. doi: 10.3390/bioengineering9070270.

DOI:10.3390/bioengineering9070270
PMID:35877321
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9312272/
Abstract

Universal chromatic dental resin-based composites were recently developed in an attempt to speed up the restoration process with the aim of making it easier for the practitioner to decide on a suitable shade and to avoid time-consuming matching and mixing of materials. The way in which color is created in the analyzed universal chromatic materials is innovative, as it is not only induced by selective light absorption via pigments (Venus Diamond ONE, Venus Pearl ONE), as is usual in regular composites (Charisma Classic, Charisma Topaz, Venus, Venus Diamond), but also by selective light reflection via particularized microstructures (Omnichroma). Material properties were assessed at 24 h post-polymerization and after artificial aging. Flexural strength (n = 20) and modulus were measured in a 3-point-bending test and complemented with fractography and Weibull analysis. Quasi-static (Martens, Vickers, and indentation hardness; elastic and total indentation work; creep, indentation depth) and viscoelastic (storage, loss, and indentation moduli; loss factor) behavior (n = 6) was measured by a depth-sensing indentation test equipped with a DMA module. The nanoscale silica/zirconia polymer core-shell structure in the structural-colored material induces similar or poorer mechanical properties compared with pigment-colored materials, which is related to the higher polymer content. For all materials, aging shows a clear influence on the measured properties, with the degree of degradation depending on the measurement scale.

摘要

通用色度牙科树脂基复合材料最近被开发出来,试图加快修复过程,目的是让从业者更容易确定合适的颜色,并避免耗时的材料匹配和混合。在所分析的通用色度材料中产生颜色的方式具有创新性,因为它不仅像常规复合材料(魅力经典、魅力黄玉、维纳斯、维纳斯钻石)那样通过颜料(维纳斯钻石一号、维纳斯珍珠一号)的选择性光吸收来产生颜色,还通过特定的微观结构(全彩)的选择性光反射来产生颜色。在聚合后24小时和人工老化后评估材料性能。在三点弯曲试验中测量弯曲强度(n = 20)和模量,并辅以断口分析和威布尔分析。通过配备动态热机械分析模块的深度传感压痕试验测量准静态(马滕斯硬度、维氏硬度和压痕硬度;弹性和总压痕功;蠕变、压痕深度)和粘弹性(储能模量、损耗模量和压痕模量;损耗因子)行为(n = 6)。与颜料着色材料相比,结构着色材料中的纳米级二氧化硅/氧化锆聚合物核壳结构导致相似或更差的机械性能,这与更高的聚合物含量有关。对于所有材料,老化对所测量的性能有明显影响,降解程度取决于测量尺度。

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