光诱导、铜催化的杂芳烃的直接全氟烷基化反应。
Photoinduced, copper-catalysed direct perfluoroalkylation of heteroarenes.
机构信息
Laboratoire de Chimie Organique, Service de Chimie et PhysicoChimie Organiques, Université libre de Bruxelles (ULB), Avenue F. D. Roosevelt 50, CP160/06, 1050 Brussels, Belgium.
Laboratoire de Chimie Organique et Photochimie, Service de Chimie et PhysicoChimie Organiques, Université libre de Bruxelles (ULB), Avenue F. D. Roosevelt 50, CP160/07, 1050 Brussels, Belgium.
出版信息
Chem Commun (Camb). 2022 Aug 11;58(65):9080-9083. doi: 10.1039/d2cc02146c.
An efficient and general process is reported for the photoinduced, copper-catalysed direct perfluoroalkylation of C-H bonds in a broad range of heteroarenes with commercially available perfluoroalkyl iodides. This redox neutral process is simply based on the use of [Cu(bcp)DPEPhos]PF as the photoredox catalyst in the presence of potassium acetate and smoothly operates at room temperature.
本文报道了一种高效、通用的光诱导、铜催化的直接 C-H 键全氟烷基化反应，该反应可在广泛的杂芳烃中进行，使用的是商业可得的全氟碘代烷和[Cu(bcp)DPEPhos]PF 作为光氧化还原催化剂，在醋酸钾的存在下，在室温下顺利进行，该过程为氧化还原中性。
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