Chen Weijiong, Ren Wangping, Kennedy Niall, Hamidian M H, Uchida S, Eisaki H, Johnson Peter D, O'Mahony Shane M, Davis J C Séamus
Clarendon Laboratory, University of Oxford, Oxford OX1 3PU, United Kingdom.
Department of Physics, University College Cork, Cork T12 R5C, Ireland.
Proc Natl Acad Sci U S A. 2022 Aug 2;119(31):e2206481119. doi: 10.1073/pnas.2206481119. Epub 2022 Jul 27.
Electron-pair density wave (PDW) states are now an intense focus of research in the field of cuprate correlated superconductivity. PDWs exhibit periodically modulating superconductive electron pairing that can be visualized directly using scanned Josephson tunneling microscopy (SJTM). Although from theory, intertwining the -wave superconducting (DSC) and PDW order parameters allows a plethora of global electron-pair orders to appear, which one actually occurs in the various cuprates is unknown. Here, we use SJTM to visualize the interplay of PDW and DSC states in BiSrCaCuO at a carrier density where the charge density wave modulations are virtually nonexistent. Simultaneous visualization of their amplitudes reveals that the intertwined PDW and DSC are mutually attractive states. Then, by separately imaging the electron-pair density modulations of the two orthogonal PDWs, we discover a robust nematic PDW state. Its spatial arrangement entails Ising domains of opposite nematicity, each consisting primarily of unidirectional and lattice commensurate electron-pair density modulations. Further, we demonstrate by direct imaging that the scattering resonances identifying Zn impurity atom sites occur predominantly within boundaries between these domains. This implies that the nematic PDW state is pinned by Zn atoms, as was recently proposed [Lozano , 103, L020502 (2021)]. Taken in combination, these data indicate that the PDW in BiSrCaCuO is a vestigial nematic pair density wave state [Agterberg 91, 054502 (2015); Wardh and Granath arXiv:2203.08250].
电子对密度波(PDW)态如今是铜酸盐关联超导领域的研究热点。PDW呈现出周期性调制的超导电子配对,可通过扫描约瑟夫森隧穿显微镜(SJTM)直接可视化。尽管从理论上讲,将d波超导(DSC)和PDW序参量交织会使大量全局电子对序出现,但在各种铜酸盐中实际出现的是哪一种尚不清楚。在此,我们使用SJSJ在电荷密度波调制几乎不存在的载流子密度下,使用SJTM来可视化BiSrCaCuO中PDW和DSC态的相互作用。对它们振幅的同时可视化显示,相互交织的PDW和DSC是相互吸引的状态。然后,通过分别对两个正交PDW的电子对密度调制进行成像,我们发现了一种稳健的向列型PDW态。其空间排列需要具有相反向列性的伊辛畴,每个畴主要由单向且与晶格相称的电子对密度调制组成。此外,我们通过直接成像证明,识别Zn杂质原子位置的散射共振主要出现在这些畴之间的边界内。这意味着向列型PDW态被Zn原子钉扎,正如最近所提出的那样[洛萨诺,《物理评论快报》103,L020502(2021)]。综合来看,这些数据表明BiSrCaCuO中的PDW是一种残余的向列型对密度波态[阿特伯格,《物理评论B》91,054502(2015);沃德和格拉纳特,arXiv:2203.08250]。