Synthesis and Properties of Stable 20π Porphyrinoids.

The 20π porphyrinoids are immediate higher homologues of 18π porphyrins and differ from porphyrins in aromaticity which in turn affects the structure, properties and chemical reactivities. Research over the years indicated that the 20π porphyrinoids can be stabilized as non-aromatic/anti-aromatic or Mobius aromatic macrocycles using different strategies such as core-modification of porphyrins, non-metal/metal complexation of porphyrins, peripheral modification of porphyrins and expanded porphyrinoids. The structural properties such as aromaticity of the macrocycle can be controlled by choosing the right synthetic strategy. This review will provide an overview of the development in the chemistry of 20π porphyrinoids giving emphasize on the synthesis, structure and electronic properties of these macrocycles which have huge potential for various applications.