Synthesis of adjustable {312}/{004} facet heterojunction MWCNTs/BiOI photocatalyst for ofloxacin degradation: Novel insights into the charge carriers transport.

Multi-wall carbon nanotubes (MWCNTs) with high electrical conductivity are commonly accounted as the ideal additives to enhance the charge surface migration efficiency in photocatalysis. Theoretically, the MWCNTs-modified binary photocatalysts have potential for the change of nanocrystal structure. Herein, we reports an adjustable {312}/{004}facet heterojunction MWCNTs/BiOI nanocomposite. Interestingly, the synergistic effect of {312}/{004}facet heterojunction and MWCNTs can effectively accelerate the spatial charge carriers transport. A novel {312}/{004}facet "S-scheme" pathway was proven to be the dominated pathway for the enhancement of spatial charge carriers. As a result, the MWCNTs-{312}/{004}BiOI composites exhibited superior photocatalytic oxidation efficiency for a representative antibiotics ofloxacin photodegradation. Density functional theory (DFT) calculation and LC-MS/MS analysis confirmed that the possible dealkylation and oxidation pathways could be found in OFL degradation. This work provides novel insights for the relationship between charge carrier transport and facet structure-property.