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三氧化二锑对用于化学镀金属的激光活化涂层中所需前驱体用量的影响。

The Effect of Antimony (III) Oxide on the Necessary Amount of Precursors Used in Laser-Activated Coatings Intended for Electroless Metallization.

作者信息

Jagodziński Bartłomiej, Rytlewski Piotr, Moraczewski Krzysztof, Trafarski Andrzej, Karasiewicz Tomasz

机构信息

Institute of Materials Engineering, Kazimierz Wielki University, 85-064 Bydgoszcz, Poland.

出版信息

Materials (Basel). 2022 Jul 25;15(15):5155. doi: 10.3390/ma15155155.

Abstract

The article presents research on the potential use of organometallic compounds with the addition of antimony (III) oxide SbO as a coating additive that will make coatings susceptible to electroless metallization after prior surface irradiation with 193 nm wavelength laser radiation and a different number of laser pulses. The surface modification and activation effects were assessed by optical-imagining as well as by scanning electron microscopy (SEM) with energy dispersive analysis (EDX). It was found that the presence of SbO in the coating made it possible to reduce the content of the copper complex, causing an intensive surface ablation, resulting in the formation of a conical structure with a higher content of metallic copper nuclei.

摘要

本文介绍了关于有机金属化合物与氧化锑(III)(SbO)作为涂层添加剂潜在用途的研究,添加该添加剂后,在先用波长为193nm的激光辐射及不同数量的激光脉冲对表面进行辐照后,涂层将易于进行化学镀金属。通过光学成像以及带有能量色散分析(EDX)的扫描电子显微镜(SEM)对表面改性和活化效果进行了评估。结果发现,涂层中SbO的存在使得能够降低铜络合物的含量,从而引起强烈的表面烧蚀,导致形成具有较高金属铜核含量的锥形结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8d9d/9330673/9bb3ee3f5fad/materials-15-05155-g001.jpg

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