Assiut and New Valley Company for Water and Wastewater, Asyut, Egypt.
Department of Chemistry, Faculty of Science, New Valley University, Kharga, 72511, Egypt.
Environ Geochem Health. 2023 May;45(5):2277-2290. doi: 10.1007/s10653-022-01340-7. Epub 2022 Aug 8.
Calcium Hardness (Ca. H) and total Hardness ions in drinkable groundwater cause great problems for the entire world especially, the population communities which are located far from surface water sources. The present study investigates the use of Sodalite Bearing Modified Illite (SBMI) as a sustainable and new technique to eliminate these ions from drinkable groundwater to compatible with the instruction of the World Health Organization. The methodology was achieved by using a new method to remove these ions' excess calcium Hardness and total Hardness depending on two main processes; the adsorption as a first step and the coagulation-flocculation-sedimentation process as a second step. The results of this study were achieved through conducting three tasks; (1) Chemical analysis surveys for all the groundwater wells, to determine the areas which are more affected by these salts, and plot them on the location maps. (2) Conducting the alkaline modification of the Illite ore to obtain the (SBMI) which has a high surface area and high adsorption ability, and it had been characterized by using XRD, XRF, SEM, and FTIR techniques. (3) The experimental studies were conducted to evaluate the effect of the modified Illite on raw groundwater containing a high concentration of hardness ions, through the batch studies to determine the factors which affected its ability for removing these ions from groundwater. The present study illustrated that the removing efficiency for both total hardness (Ca. H + Mg. H) and calcium hardness (Ca. H) reached about 98%. Finally, the present study recommended using this technique, when there is a requirement for large quantities of treated water at a low cost.
饮用水中钙硬度 (Ca.H) 和总硬度离子对全世界,特别是远离地表水水源的人口社区造成了很大的问题。本研究探讨了利用含沸石改性伊利石 (SBMI) 作为一种可持续和新技术,从饮用水中去除这些离子,使其符合世界卫生组织的指示。该方法通过使用一种新方法来去除这些离子的过量钙硬度和总硬度,该方法依赖于两个主要过程;吸附作为第一步,以及凝聚-絮凝-沉淀过程作为第二步。本研究的结果是通过进行三项任务来实现的;(1) 对所有地下水井进行化学分析调查,以确定受这些盐影响更大的地区,并将其绘制在位置图上。(2) 对伊利石矿石进行碱性改性,以获得具有高表面积和高吸附能力的 (SBMI),并通过 XRD、XRF、SEM 和 FTIR 技术对其进行了表征。(3) 通过批量研究评估改性伊利石对含有高浓度硬度离子的原地下水的影响,以确定影响其从地下水中去除这些离子能力的因素。本研究表明,总硬度 (Ca.H + Mg.H) 和钙硬度 (Ca.H) 的去除效率均达到约 98%。最后,本研究建议在需要大量低成本处理水时使用该技术。