Salama Amgad, Van Geel Paul J, Kou Jisheng, Husein Maen M
Process System Engineering, University of Regina, Regina, Saskatchewan S4S 0A2, Canada.
Civil & Environmental Engineering Department, Carleton University, Ottawa, Ontario K1S 5B6, Canada.
Langmuir. 2022 Aug 23;38(33):10274-10287. doi: 10.1021/acs.langmuir.2c01620. Epub 2022 Aug 9.
The emergence of a droplet from a capillary tube opening into a reservoir is an important phenomenon in several applications. In this work, we are particularly interested in this phenomenon in an attempt to highlight the physics behind droplet appearance. The emergence of a droplet from a tube opening into a reservoir under quasi-static conditions passes through three stages. The first stage starts when the meniscus in the tube reaches the exit. At this moment, the meniscus intersects the wall of the tube at the equilibrium contact angle. The interface then develops until its radius of curvature becomes equal to the tube radius. During this stage, the capillary pressure increases. In the second stage, the interface continues to evolve with its radius of curvature increasing until the static contact angle with respect to the surface of the reservoir is achieved. This marks the end of the second stage and the start of the third in which the contact line (CL) starts to depart the tube opening along the reservoir surface and the contact angle remains constant. Analytical models for the three stages have been derived based on the law of conservation of linear momentum. The models account for pressure, gravitational, capillary, and viscous forces, while inertia force is ignored. The model can predict the profiles of the mean velocity in the tube, the capillary pressure, and the evolution of the contact angle. In addition, a computational fluid dynamics (CFD) simulation has been conducted to provide a framework for validation and verification of the developed model. The CFD simulation shows qualitative behavior in terms of snapshots of the emerging droplet with time similar to that speculated by the analytical model. In addition, quantitative comparisons with respect to velocity, pressure, and volume profiles of the droplet show very good agreement, which builds confidence in the modeling approach.
液滴从毛细管开口进入储液器的现象在多个应用中是一个重要现象。在这项工作中,我们对这一现象特别感兴趣,试图突出液滴出现背后的物理原理。在准静态条件下,液滴从管开口进入储液器的过程经历三个阶段。第一阶段始于管内弯月面到达出口之时。此时,弯月面以平衡接触角与管壁相交。然后界面发展,直至其曲率半径等于管半径。在此阶段,毛细管压力增加。在第二阶段,界面继续演化,其曲率半径增大,直至达到相对于储液器表面的静态接触角。这标志着第二阶段结束和第三阶段开始,在第三阶段,接触线开始沿着储液器表面离开管开口,接触角保持不变。基于线性动量守恒定律推导了这三个阶段的解析模型。这些模型考虑了压力、重力、毛细管力和粘性力,而忽略了惯性力。该模型可以预测管内平均速度的分布、毛细管压力以及接触角的演变。此外,还进行了计算流体动力学(CFD)模拟,以提供一个框架来验证和核实所开发的模型。CFD模拟显示,就新兴液滴随时间的快照而言,其定性行为与解析模型推测的相似。此外,与液滴的速度、压力和体积分布的定量比较显示出非常好的一致性,这增强了对建模方法的信心。