Removal of pharmaceuticals by vertical flow constructed wetland with different configurations: Effect of inlet load and biochar addition in the substrate.

Pharmaceuticals (PCs) residues are considered an emerging threat to the environment due to their persistency, ecotoxicity and bioaccumulative nature. To study the PC (amoxicillin, AMX; caffeine, CF; ibuprofen, IBU) removal efficiency of vertical flow constructed wetland (VFCW), three setups of VFCWs were configured: SB (substrate matrix + biochar (BC)); SBP (substrate matrix + BC + plant); SP (substrate matrix + plant) and changes in effluent PC load was estimated at 24, 48, 72, 96, 120, 144 and 168 h intervals. SBP with an influent load of 1,000 μg L showed the maximum removals of 75.51% (AMX), 87.53% (CF), and 79.93% (IBU) significantly higher than that of SB and SP (p < 0.00). Results showed an inverse relationship between removal efficacy and influent PCs loading. The average removal (%) by VFCWS (of all studied setups) was in the order: 66.20 > 47.88 > 39.0 (IBU), 56.56 > 42.12 > 34.36 (AMX), and 74.13 > 64.0 > 52.07 (CF) with 1,000, 5,000 > 10,000 μg L influent load, respectively. The maximum removal of COD, NH-N, and NO-N was recorded at 88.8%, 83.1%, and 64.9%, respectively in SBP, and their removal was hardly affected by influent PC concentration. In summary, planted VFCW spiked with BC could be a viable approach for the removal of PCs in wastewater. The impact of PC load on plant toxicity in VFCWs can be taken as a research problem for future work in this series.