Fujita Masaki, Haketa Yohei, Tanaka Hiroki, Yasuda Nobuhiro, Maeda Hiromitsu
Department of Applied Chemistry, College of Life Sciences, Ritsumeikan University, Kusatsu, 525-8577, Japan.
Diffraction and Scattering Division, Japan Synchrotron Radiation Research Institute, Sayo, 679-5198, Japan.
Chem Commun (Camb). 2022 Sep 1;58(71):9870-9873. doi: 10.1039/d2cc02345h.
Various counteranions of the thiaporphyrin-Ni complex as a π-electronic cation were exchanged for preparing stable ion pairs. The ion-pairing assembling modes, which included contributions of charge-by-charge and charge-segregated modes, and properties depended on the geometries and electronic states of the counteranions.
作为π电子阳离子的硫杂卟啉 - 镍配合物的各种抗衡阴离子被交换以制备稳定的离子对。离子对组装模式包括逐电荷模式和电荷分离模式的贡献，其性质取决于抗衡阴离子的几何形状和电子状态。
