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基于机械压力-真空场的废气化细渣高效脱水:脱水特性、能量优化及潜在环境效益。

Efficient dewatering of waste gasification fine slag based on mechanical pressure-vacuum fields: Dewatering characteristics, energy optimization and potential environmental benefits.

机构信息

School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou 221116, PR China; National Engineering Research Center of Coal Preparation and Purification, China University of Mining and Technology, Xuzhou 221116, PR China.

School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou 221116, PR China.

出版信息

J Environ Manage. 2022 Oct 15;320:115881. doi: 10.1016/j.jenvman.2022.115881. Epub 2022 Aug 8.

Abstract

Landfill is the major waste disposal method of high-moisture coal gasification fine slag (GFS) which causes the pollution of soil and water and brings the waste of resources. GFS efficient dewatering is an urgent problem to be solved, which is beneficial to realize its resource utilization. In this paper, mechanical pressure and vacuum coupling energy fields are applied to carry out the dewatering processes of GFS. The pressure field provides strong power for water migration, which makes water leave the particle system, while the vacuum field provides traction for water removal from system. The fine slag produced from Coal-to-methanol (named JC) with larger size particles tends to form "bridging" frameworks among particles, which provides water occurrence space and increases the moisture migration resistance. The mechanical dewatering process has an energy advantage interval, when the sample moisture is reduced to a certain degree, the mechanical force field is mainly used for particle friction and breakage but not for moisture migration. Through dewatering process energy optimization, high moisture gasification fine slag can be removed about 15% water within 30s and energy consumption of efficient dewatering is 2.63 kJ/g which is much lower than that of drying. Efficient dewatering is benefit to the GFS recycling which reduces hazardous materials release to environment. The potential effects of high efficiency dewatering process on GFS resource utilization and the possible eco-design framework for products recycled from the waste GFS were proposed. The research results will provide theoretical guidance for the gasification fine slag efficient dewatering and is benefit to the environment.

摘要

垃圾填埋是高水分煤气化细渣(GFS)的主要处理方法,会造成土壤和水的污染,并浪费资源。GFS 的高效脱水是亟待解决的问题,有利于实现其资源利用。本文应用机械压力和真空耦合能量场对 GFS 进行脱水处理。压力场为水分迁移提供强大动力,使水分离开颗粒系统,而真空场为系统中水分的去除提供牵引力。煤制甲醇(命名为 JC)产生的细渣颗粒较大,容易在颗粒之间形成“桥接”框架,为水的存在提供空间,并增加水分迁移阻力。机械脱水过程具有能量优势区间,当样品水分降低到一定程度时,机械力场主要用于颗粒摩擦和破碎,而不是水分迁移。通过对脱水过程进行能量优化,可以在 30s 内去除高水分煤气化细渣约 15%的水分,高效脱水的能耗为 2.63kJ/g,远低于干燥的能耗。高效脱水有利于 GFS 的回收利用,减少有害物质释放到环境中。提出了高效脱水工艺对 GFS 资源利用的潜在影响以及从废弃 GFS 中回收产品的可能生态设计框架。研究结果将为煤气化细渣的高效脱水提供理论指导,有利于环境保护。

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