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用于自清洁、防腐蚀和油水分离的基于蜡烛烟灰的电喷雾超疏水涂层

Candle Soot-Based Electrosprayed Superhydrophobic Coatings for Self-Cleaning, Anti-Corrosion and Oil/Water Separation.

作者信息

Zhang Yuting, Lei Tingping, Li Shuangmin, Cai Xiaomei, Hu Zhiyuan, Wu Weibin, Lin Tianliang

机构信息

College of Mechanical Engineering and Automation, Huaqiao University, Xiamen 361021, China.

Fujian Provincial Key Laboratory of Special Energy Manufacturing, Huaqiao University, Xiamen 361021, China.

出版信息

Materials (Basel). 2022 Aug 1;15(15):5300. doi: 10.3390/ma15155300.

Abstract

The interest in candle soot (CS)-based superhydrophobic coatings has grown rapidly in recent years. Here, a simple and low-cost process has been developed for the fabrication of CS-based superhydrophobic coatings through electrospraying of the composite cocktail solution of CS and polyvinylidene fluoride (PVDF). Results show that the superhydrophobicity of the coating closely relates to the loading amount of CS which results in coatings with different roughnesses. Specifically, increasing the CS amount (not more than 0.4 g) normally enhances the superhydrophobicity of the coating due to higher roughness being presented in the produced microspheres. Further experiments demonstrate that the superhydrophobicity induced in the electrosprayed coating results from the synergistic effect of the cocktail solution and electrospray process, indicating the importance of the coating technique and the solution used. Versatile applications of CS-based superhydrophobic coatings including self-cleaning, anti-corrosion and oil/water separation are demonstrated. The present work provides a convenient method for the fabrication of CS-based superhydrophobic coatings, which is believed to gain great interest in the future.

摘要

近年来,基于蜡烛烟灰(CS)的超疏水涂层受到的关注迅速增长。在此,通过电喷雾CS与聚偏二氟乙烯(PVDF)的复合混合溶液,开发了一种简单且低成本的制备基于CS的超疏水涂层的方法。结果表明,涂层的超疏水性与CS的负载量密切相关,这导致涂层具有不同的粗糙度。具体而言,增加CS的量(不超过0.4 g)通常会提高涂层的超疏水性,因为在生成的微球中呈现出更高的粗糙度。进一步的实验表明,电喷雾涂层中诱导的超疏水性源于混合溶液和电喷雾过程的协同效应,这表明了涂层技术和所用溶液的重要性。展示了基于CS的超疏水涂层的多种应用,包括自清洁、防腐和油水分离。目前的工作为制备基于CS的超疏水涂层提供了一种简便方法,相信在未来会引起极大的兴趣。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/690e/9370047/b3831173a335/materials-15-05300-g001.jpg

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