Accelerating the Reaction Kinetics of NaCO-Activated Slag Mortars by Calcined Recycled Concrete Fines.

Sodium carbonate (NaCO), an environmentally friendly activator, has been shown to have vast potential for the development of sustainable alkali-activated slag mortars. However, NaCO-activated slag mortars exhibit a delayed reaction process and limited early-age strength development, restricting their wider application. In this work, the recycled concrete fines were calcined at a temperature of 800 °C for 1 h and then used as an auxiliary activator to improve the reaction kinetics of NaCO-activated slag mortars. The impact of the calcined recycled concrete fines (CRCF) dosage and NaCO concentration on the compressive strength, hydration kinetics, and phase assemblage of mortars was evaluated. The results show that CRCF can react directly with NaCO in the early stages, swiftly removing the CO in aqueous solution and providing an alkaline environment suitable for the dissolution of slag. This promotes the development of C-(A)-S-H, hydrotalcite, hemicarbonate, and monocarbonate. The hydration process and strength-giving phase of mortars can be improved further, as an increase in NaCO concentration increases the initial alkaline content. Additionally, the most remarkable compressive strength value of 39.2 MPa was observed at 28 days in the mortar with 6% sodium oxide equivalent (NaO-E) of NaCO and 15% CRCF because of the synergistic effect of CRCF and NaCO.