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用于高温应用的h-BN和GNP增强聚合物复合材料的力学和热特性的实验与计算研究

Experimental and Computational Study of Mechanical and Thermal Characteristics of h-BN and GNP Infused Polymer Composites for Elevated Temperature Applications.

作者信息

Choukimath Mantesh C, Banapurmath Nagaraj R, Riaz Fahid, Patil Arun Y, Jalawadi Arun R, Mujtaba M A, Shahapurkar Kiran, Khan T M Yunus, Alsehli Mishal, Soudagar Manzoore Elahi M, Fattah I M R

机构信息

School of Mechanical Engineering, KLE Technological University, Hubballi 580031, India.

Mechanical Engineering Department, Abu Dhabi University, Abu Dhabi P.O. Box 59911, United Arab Emirates.

出版信息

Materials (Basel). 2022 Aug 5;15(15):5397. doi: 10.3390/ma15155397.

Abstract

Polymer-based nanocomposites are being considered as replacements for conventional materials in medium to high-temperature applications. This article aims to discover the synergistic effects of reinforcements on the developed polymer-based nanocomposite. An epoxy-based polymer composite was manufactured by reinforcing graphene nanoplatelets (GNP) and h-boron nitride (h-BN) nanofillers. The composites were prepared by varying the reinforcements with the step of 0.1 from 0.1 to 0.6%. Ultrasonication was carried out to ensure the homogenous dispersion of reinforcements. Mechanical, thermal, functional, and scanning electron microscopy (SEM) analysis was carried out on the novel manufactured composites. The evaluation revealed that the polymer composite with GNP 0.2 by wt % has shown an increase in load-bearing capacity by 265% and flexural strength by 165% compared with the pristine form, and the polymer composite with GNP and h-BN 0.6 by wt % showed an increase in load-bearing capacity by 219% and flexural strength by 114% when compared with the pristine form. Furthermore, the evaluation showed that the novel prepared nanocomposite reinforced with GNP and h-BN withstands a higher temperature, around 340 °C, which is validated by thermogravimetric analysis (TGA) trials. The numerical simulation model is implemented to gather the synthesised nanocomposite's best composition and mechanical properties. The minor error between the simulation and experimental data endorses the model's validity. To demonstrate the industrial applicability of the presented material, a case study is proposed to predict the temperature range for compressor blades of gas turbine engines containing nanocomposite material as the substrate and graphene/h-BN as reinforcement particles.

摘要

基于聚合物的纳米复合材料正被视为中高温应用中传统材料的替代品。本文旨在发现增强材料对已开发的基于聚合物的纳米复合材料的协同效应。通过增强石墨烯纳米片(GNP)和h-氮化硼(h-BN)纳米填料制备了一种环氧基聚合物复合材料。通过以0.1%的步长从0.1%变化到0.6%来改变增强材料的含量,从而制备复合材料。进行超声处理以确保增强材料均匀分散。对新制备的复合材料进行了力学、热学、功能和扫描电子显微镜(SEM)分析。评估结果显示,与原始形式相比,含0.2 wt% GNP的聚合物复合材料的承载能力提高了265%,弯曲强度提高了165%;与原始形式相比,含0.6 wt% GNP和h-BN的聚合物复合材料的承载能力提高了219%,弯曲强度提高了114%。此外,评估表明,用GNP和h-BN增强的新制备的纳米复合材料能够承受更高的温度,约340℃,这通过热重分析(TGA)试验得到了验证。实施数值模拟模型以获取合成纳米复合材料的最佳组成和力学性能。模拟数据与实验数据之间的微小误差证明了该模型的有效性。为了证明所提出材料的工业适用性,提出了一个案例研究,以预测燃气涡轮发动机压缩机叶片的温度范围,该叶片以纳米复合材料为基体,以石墨烯/h-BN为增强颗粒。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1be0/9370023/f500470bc973/materials-15-05397-g001.jpg

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