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利用沙枣树皮合成 MnFeO@TiO 磁性纳米复合材料,用于高效光催化降解水溶液中的腐殖酸。

Biosynthesis of MnFeO@TiO magnetic nanocomposite using oleaster tree bark for efficient photocatalytic degradation of humic acid in aqueous solutions.

机构信息

Medical Toxicology and Drug Abuse Research Center (MTDRC), Birjand University of Medical Sciences (BUMS), Birjand, Iran.

出版信息

Environ Sci Pollut Res Int. 2023 Jan;30(2):3862-3871. doi: 10.1007/s11356-022-22518-7. Epub 2022 Aug 12.

DOI:10.1007/s11356-022-22518-7
PMID:35960468
Abstract

The presence of humic acid compounds in water resources, as one of the precursors of Trihalomethanes and Holoacetic acids, causes health problems for many communities. The aim of this research study was to investigate the photocatalytic degradation efficiency of humic acid using MnFeO@TiO nanoparticles which produced by green synthesis method. The synthesis of metal nanoparticles using plant extracts and the study of their catalytic performance is a relatively new topic. Many chemical techniques have been proposed for the synthesis of MnFeO@TiO nanoparticles, but green synthesis has received much attention due to its availability, simplicity, and non-toxicity. The properties of synthesized nanoparticles were determined by SEM, FT-IR, XRD, EDS, and DLS analysis. The results of the study showed that under optimal experimental conditions (pH = 3, nanocomposite dose = 0.03 g/L, humic acid initial concentration = 2 mg/L, and contact time = 20 min), it is possible to achieve maximum degradation of humic acid. Therefore; MnFeO@TiO nanoparticles have high efficiency for removing of humic acid from aqueous solutions under UV light.

摘要

水中腐殖酸化合物的存在是三卤甲烷和卤乙酸的前体之一,会对许多社区的健康造成问题。本研究旨在探讨使用 MnFeO@TiO 纳米粒子光催化降解腐殖酸的效率,该纳米粒子是通过绿色合成方法制备的。利用植物提取物合成金属纳米粒子及其催化性能的研究是一个相对较新的课题。许多化学技术已被提出用于合成 MnFeO@TiO 纳米粒子,但由于其可用性、简单性和非毒性,绿色合成受到了更多关注。合成纳米粒子的性质通过 SEM、FT-IR、XRD、EDS 和 DLS 分析来确定。研究结果表明,在最佳实验条件下(pH=3、纳米复合材料剂量=0.03g/L、腐殖酸初始浓度=2mg/L 和接触时间=20min),可以实现腐殖酸的最大降解。因此,在 UV 光下,MnFeO@TiO 纳米粒子对去除水溶液中的腐殖酸具有高效性。

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