Aggregation-Induced Emission of Gold Nanoclusters by Ionic Liquids for White Light-Emitting Diode and Multiple-Ion Probe Applications.

White light-emitting diodes (WLEDs) require stable luminophores with bright emission, a large Stokes shift, and good processability. Herein, we fabricate WLEDs on the basis of synergetic aggregation-induced emission (AIE) of Au nanoclusters (NCs) induced by ionic liquids. Au NCs with orange emission at 615 nm are electrostatically bonded to 1-ethyl-3-methyl-imidazolium acetate (EmimOAc). The electrostatic bonding not only introduces complementary blue emission (from EmimOAc) into Au NCs but also enhances cluster emission via an intercluster AIE mechanism. Overall white emission of Au NC-EmimOAc composites can be further improved by their encapsulation into nanogels templated by cationic chitosan. Color conversion films constructed from these nanogels manifest ultrabright white emission on a commercial GaN ultraviolet LED chip, featuring a CIE 1931 color coordinate of (0.366, 0.368) and greatly enhanced mechanical strength. By properly selecting ionic liquids, we are also able to achieve multiple-ion detection of Cu, Sn, and Fe.