University of Minnesota - Twin Cities, 207 Pleasant St SE, Minneapolis, MN, 55455, USA.
Chem Commun (Camb). 2022 Aug 25;58(69):9586-9593. doi: 10.1039/d2cc03516b.
3-Ethyl-6-vinyltetrahydro-2-pyran-2-one (EVP) is a CO-derived lactone synthesized Pd-catalyzed telomerization of butadiene. As EVP is 28.9% by weight CO, it has received significant recent attention as an intermediary for the synthesis of high CO-content polymers. This article provides an overview of strategies for the polymerization of EVP to a wide variety of polymer structures, ranging from radical polymerizations to ring-opening polymerizations, that each take unique advantage of the highly functionalized lactone.
3-乙基-6-乙烯基四氢-2-吡喃-2-酮（EVP）是一种由 Pd 催化丁二烯齐聚得到的 CO 衍生内酯。由于 EVP 含有 28.9%的 CO 质量分数，它作为合成高 CO 含量聚合物的中间体，最近受到了广泛关注。本文综述了 EVP 聚合为各种聚合物结构的策略，包括自由基聚合和开环聚合，这些聚合方法都充分利用了高度官能化的内酯。
