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利用海上石油开发的水基钻井岩屑制造轻集料:中国渤海油田的案例研究。

Utilization of water-based drilling cuttings from offshore oil development to manufacture lightweight aggregates: a case study in the Bohai oil field, China.

作者信息

Liu Wenshi, Li Maochuan, Yuan Hui, Geng Tie, Li Xiaoling, Zhang Zhongliang, He Dongxue

机构信息

College of Chemistry and Chemical Engineering, Southwest Petroleum University, No. 8 Xin Du Da Dao, Xin Du District, Chengdu, 610500, China.

Environmental Engineering Division, Chongqing Chemical Engineering Design and Research Institute Company Limited, Chongqing, 400050, China.

出版信息

Environ Sci Pollut Res Int. 2023 Jan;30(2):4837-4852. doi: 10.1007/s11356-022-22393-2. Epub 2022 Aug 17.

DOI:10.1007/s11356-022-22393-2
PMID:35974276
Abstract

Offshore water-based drilling cuttings (OWDC) are by-products of offshore oil-well drilling, whose effective management has become an urgent environmental and engineering issue. This study investigated the feasibility of recycling OWDC from the Bohai oilfield in China as a raw material for manufacturing lightweight aggregates (LWA). The effects of OWDC content (0-50%), preheating temperature (300-500 °C), and sintering temperature (1050-1200 °C) on the physical-mechanical performance of the resulting LWA were investigated through single-factor experiments. The microstructural and expansion mechanism analyses were determined based on X-ray diffraction analysis, scanning electron microscopy, and energy-dispersive X-ray spectrometric microanalysis. The results showed that under the optimum preparation conditions (mass ratio of OWDC and fly ash at 50:50, preheating at 400 °C for 30 min, and sintering at 1150 °C for 30 min), the OWDC-based LWA could meet the requirements of Chinese standard GB/T 17431.1-2010. The incorporation of OWDC lowered the aggregate melting points and promoted dense structure formation inside the aggregates due to the presence of flux agents (e.g., NaO and KO). Besides, OWDC additions promoted the formation of the liquid phase and gases inside the pellets, which was beneficial to the expansion behavior and lightweight performance of the aggregates. However, OWDC also had a negative effect on the compressive strength of the aggregates owing to the formation of enlarged pores. Furthermore, the results of the environmental performance tests indicated that the LWA were safe for the environment. This study provides a reference for recycling water-based drilling cuttings from offshore oilfields and contributes to the circular economy.

摘要

海洋水基钻井岩屑(OWDC)是海洋油井钻探的副产品,其有效管理已成为一个紧迫的环境和工程问题。本研究调查了将中国渤海油田的OWDC作为制造轻骨料(LWA)的原材料进行回收利用的可行性。通过单因素实验研究了OWDC含量(0-50%)、预热温度(300-500℃)和烧结温度(1050-1200℃)对所得LWA物理力学性能的影响。基于X射线衍射分析、扫描电子显微镜和能量色散X射线光谱微分析确定了微观结构和膨胀机理分析。结果表明,在最佳制备条件下(OWDC与粉煤灰质量比为50:50,400℃预热30min,1150℃烧结30min),基于OWDC的LWA能够满足中国标准GB/T 17431.1-2010的要求。由于助熔剂(如NaO和KO)的存在,OWDC的加入降低了骨料的熔点并促进了骨料内部致密结构的形成。此外,OWDC的添加促进了球团内部液相和气体的形成,这有利于骨料的膨胀行为和轻质性能。然而,由于大孔的形成,OWDC对骨料的抗压强度也有负面影响。此外,环境性能测试结果表明,LWA对环境是安全的。本研究为海洋油田水基钻井岩屑的回收利用提供了参考,有助于循环经济的发展。

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