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Crystal structure of (2)-1-(4-eth-oxy-phen-yl)-3-(4-fluoro-phen-yl)prop-2-en-1-one.

作者信息

Bernhard Merle, Lutter Jacob C, Predecki Allison

机构信息

Department of Chemistry and Biochemistry, Shippensburg University, Shippensburg, PA 17257, USA.

Department of Chemistry and Biochemistry, University of Southern Indiana, Evansville, IN 47712, USA.

出版信息

Acta Crystallogr E Crystallogr Commun. 2022 Jul 22;78(Pt 8):821-824. doi: 10.1107/S2056989022007423. eCollection 2022 Aug 1.

Abstract

The title mol-ecule, CHFO, was synthesized by a Claisen-Schmidt condensation with 4-fluoro-benzaldehyde and 4'-eth-oxy-aceto-phenone. The torsion angles between the 4-fluoro-phenyl ring and the alkene and the 4'-eth-oxy-phenyl ring and the 2-propen-1-one are -1.2 (4) and 1.2 (3)°, respectively; however, there is a larger torsion between the bonds comprising the 2-propen-1-one unit of 12.0 (4)°. The crystal packing is stabilized by inter-molecular C-H⋯O/F hydrogen bonding, π-π stacking, and H-π inter-actions.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/684c/9361380/3c26198e5f36/e-78-00821-fig1.jpg

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