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设计水蒸气燃料盐水丝茧蛋白生物电池,用于自发光水壶和水蒸气面板。

Designing water vapor fuelled brine-silk cocoon protein bio-battery for a self-lighting kettle and water-vapor panels.

机构信息

NanoScience Technology Center, University of Central Florida, Orlando, Fl, 32826, USA.

Design Department, Indian Institute of Technology Kanpur, Kanpur, UP, 208016, India.

出版信息

Sci Rep. 2022 Aug 17;12(1):13999. doi: 10.1038/s41598-022-18211-x.

Abstract

Water vapor increases the electrical conductivity of silk cocoons, human hair, jute, and corn silk. This phenomenon is unclear. In the present study, XPS analysis of cocoons showed that water vapor reduces the surface presence of low-energy carbon species (C-C, C-H). In contrast, electron-dense, high-energy carbon species (C-N, C=C, C=O) remained unchanged, possibly enhancing surface charge hopping. While water vapor improves the conduction, the deficiency of charge carrier diminishes the effect. We increase the charge carrier by soaking the cocoon in an aqueous solution of common salt (NaCl) to amplify the current. Salt treatment followed by 2-min exposure to water vapor results in a sharp upward spike in the current (3.6 ± 1.07 mA, n = 12; mean ± SE) from the baseline (0.06 ± 0.02 mA, n = 12). After 1 h, it maintains an average value of 0.39 ± 0.12 mA; n = 12, indicating an upward shift in the baseline. Every time the cocoon charges with water vapor, the next charging cycle initiates after the cocoon dries up. Inspired by the cocoon ecology, we demonstrate an alternating 'water vapor-dry air' cycle for rapid charging and discharging of the cocoon battery. Finally, we designed a prototype of a self-lighting kettle and water-vapor panels for futuristic homes using a 'brine-silk cocoon protein bio-battery,' where moist waste heat generates electricity.

摘要

水蒸气会增加蚕丝、人发、黄麻和玉米须的电导率。这一现象尚不清楚。在本研究中,XPS 分析表明,水蒸气会减少蚕茧表面低能量碳物种(C-C、C-H)的存在。相比之下,电子密度较高的高能碳物种(C-N、C=C、C=O)保持不变,这可能增强了表面电荷跳跃。虽然水蒸气可以改善传导,但载流子的缺乏会削弱这种效果。我们通过将蚕茧浸泡在盐(NaCl)水溶液中来增加载流子,以放大电流。盐处理后,将蚕茧暴露在水蒸气中 2 分钟,会导致电流急剧上升(3.6±1.07 mA,n=12;平均值±SE),高于基线(0.06±0.02 mA,n=12)。1 小时后,它保持在 0.39±0.12 mA 的平均水平;n=12,表明基线向上移动。每次蚕茧与水蒸气充电后,下一个充电周期都会在蚕茧变干后开始。受蚕茧生态的启发,我们展示了一种交替的“水蒸气-干燥空气”循环,用于快速充放电蚕茧电池。最后,我们使用“盐水-丝茧蛋白生物电池”为未来的家庭设计了自供电水壶和水蒸气面板原型,其中湿废热产生电能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3609/9385712/9cf4281279e3/41598_2022_18211_Fig1_HTML.jpg

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