Reactivity of a di(amidoxime) ligand in the presence of Cu(II)/Ni(II).
作者信息
Liu Tingting, Liu Qian, Xue Yun, Yang Suliang, Ma Fuqiu, Tian Guoxin
机构信息
College of Nuclear Science and Technology, Harbin Engineering University, Harbin, Heilongjiang, 150001, China.
Department of Radiochemistry, China Institute of Atomic Energy, Beijing, 102413, China.
出版信息
Dalton Trans. 2022 Aug 30;51(34):12808-12811. doi: 10.1039/d2dt02223k.
PMID:35980190
Abstract
As the primary functional groups of amidoxime sorbents for uranium recovery from seawater, di(amidoxime) ligands can be cyclized into different ligands in the presence of Cu(II)/Ni(II) at different pH values. Here we first found that a linear ligand glutardiamidoxime can be catalyzed into a cyclic ligand glutarimidedioxime by Ni(II) in acidic solution.
摘要
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