Beijing Key Laboratory of Lignocellulosic Chemistry, Beijing Forestry University, Beijing 100083, China.
State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China.
Int J Mol Sci. 2022 Aug 16;23(16):9185. doi: 10.3390/ijms23169185.
Solar-driven steam generation for desalination is a facile, sustainable, and energy-saving approach to produce clean freshwater. However, the complicated fabrication process, high cost, potential environmental impact, and salt crystallization of conventional evaporators limit their large-scale application. Herein, we present a sustainable Janus evaporator based on a biopolymer sponge from the water hyacinth petiole (WHP) for high-performance solar steam generation. The freeze-dried WHP maintained its original porous structure and aligned channels well, and therefore holds the capability for rapid water transport due to strong capillary action. The WHP coated with carbon nanotubes/ethyl cellulose paste on its surface (WHP-C) gains a good photothermal property, thus achieving an efficient solar steam generation with a rate of 1.50 kg m h under 1 sun irradiation. Moreover, the WHP-C after hydrophobic modification by fluorocarbon (WHP-CH) is endowed with high water repellency and exhibits good salt resistance during long-term solar desalination. Additionally, we demonstrate that a stable wet surface that enables efficient water supply and vapor escape is also significant to the successive desalination of a solar evaporator. Our work provides new insights into the high-value utilization of biomass waste, i.e., water hyacinth, and the development of sustainable interfacial solar evaporators for the environmentally friendly production of freshwater.
用于海水淡化的太阳能蒸汽产生是一种简便、可持续和节能的方法,可以生产清洁的淡水。然而,传统蒸发器的复杂制造工艺、高成本、潜在的环境影响和盐结晶限制了它们的大规模应用。在此,我们提出了一种基于水葫芦叶柄的生物聚合物海绵的可持续性 Janus 蒸发器,用于高性能太阳能蒸汽产生。冻干的水葫芦叶柄保持了其原始的多孔结构和良好的定向通道,因此由于强毛细作用而具有快速水传输的能力。在表面涂覆碳纳米管/乙基纤维素糊(WHP-C)的水葫芦叶柄获得了良好的光热性能,因此在 1 个太阳照射下实现了 1.50 kg m h 的高效太阳能蒸汽产生。此外,经过氟碳(WHP-CH)疏水改性的 WHP-C 具有高拒水性,并在长期太阳能淡化过程中表现出良好的耐盐性。此外,我们证明了能够实现高效供水和蒸汽逸出的稳定湿表面对于太阳能蒸发器的连续脱盐也很重要。我们的工作为生物质废物(如水葫芦)的高价值利用以及用于环保生产淡水的可持续界面太阳能蒸发器的开发提供了新的见解。