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用于制造涡轮叶片的陶瓷型壳与单晶高温合金之间的界面反应机理

Interfacial Reaction Mechanism between Ceramic Mould and Single Crystal Superalloy for Manufacturing Turbine Blade.

作者信息

Yao Jiansheng, Dong Longpei, Wu Zhenqiang, Wang Lili, Shen Bin, Yang Xiaowei

机构信息

Science and Technology on Advanced High Temperature Structural Materials Laboratory, AECC Beijing Institute of Aeronautical Materials, Beijing 100095, China.

出版信息

Materials (Basel). 2022 Aug 11;15(16):5514. doi: 10.3390/ma15165514.

Abstract

Single crystal superalloys are the preferred materials for manufacturing turbine blades of advanced aero-engines, due to their excellent high temperature comprehensive performance. The interfacial reaction between alloys and ceramic mould are an important factor to influence the surface quality and service performance of the turbine blade. It is very important to reveal the interfacial reaction mechanism to improve turbine blade quality and yield rate. In this paper, the interfacial reactions between DD6 single crystal superalloy and ceramic mould were investigated by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and X-ray diffraction analysis (XRD). The results show that the main reaction products were HfO, AlO and YAlO when the yttrium oxide powders were the prime coat materials, while alloy surface suffered undesirable sand fusion; the thicknesses of the reaction layers were over 20 μm. The reaction layer can be divided into two layers, the layer close to the alloy was mainly composed of AlO and YAlO, and the layer close to the mould was composed of SiO, AlO and YAlO. Avoiding the formation of YO-AlO-SiO ternary low-melts can solve the interfacial reaction between DD6 alloy and yttrium oxide mould.

摘要

单晶高温合金因其优异的高温综合性能,是制造先进航空发动机涡轮叶片的首选材料。合金与陶瓷型壳之间的界面反应是影响涡轮叶片表面质量和服役性能的重要因素。揭示界面反应机理对于提高涡轮叶片质量和成品率具有重要意义。本文采用扫描电子显微镜(SEM)、能谱仪(EDS)和X射线衍射分析(XRD)研究了DD6单晶高温合金与陶瓷型壳之间的界面反应。结果表明,当以氧化钇粉末作为面层材料时,主要反应产物为HfO、AlO和YAlO,合金表面出现了不良的粘砂现象,反应层厚度超过20μm。反应层可分为两层,靠近合金的一层主要由AlO和YAlO组成,靠近型壳的一层由SiO、AlO和YAlO组成。避免形成YO-AlO-SiO三元低熔点物能解决DD6合金与氧化钇型壳之间的界面反应问题。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/532a/9412629/739d588f646c/materials-15-05514-g001.jpg

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