• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

基于 TPPS 的微污染物敏化光氧化—单线态氧动力学研究。

TPPS-Sensitized Photooxidation of Micropollutants-Singlet Molecular Oxygen Kinetic Study.

机构信息

Molecular Engineering Department, Lodz University of Technology, Wolczanska 213, 90-924 Lodz, Poland.

出版信息

Molecules. 2022 Aug 17;27(16):5260. doi: 10.3390/molecules27165260.

DOI:10.3390/molecules27165260
PMID:36014499
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9412460/
Abstract

Visible light-sensitized oxidation of micropollutants (MPs) in the presence of meso-tetrakis(4-sulfonatophenyl)porphyrin photosensitizers was studied. In order to explore the role of type I (ROS generation) or type II (singlet oxygen) photooxidation, radical scavengers were used to obtain insight into the mechanism of photodegradation. It was revealed that singlet oxygen is the main ROS taking part in TPPS- sensitized photooxidation of micropollutants. The interaction of MPs with O in deuterium oxide (DO) was investigated by measuring the phosphorescence lifetime of O. The rate constant (kq) for the total (physical and chemical) quenching of O by MPs was determined in a DO buffer (pD 7, 9 and 10.8). The rate constants of singlet oxygen quenching and reaction with MPs were determined, and the rate constant of excited TPPS quenching by MPs was also estimated.

摘要

研究了在 meso-四(4-磺酸钠苯基)卟啉敏化剂存在下可见光照敏化微污染物 (MPs) 的氧化作用。为了探究 I 型 (ROS 生成) 或 II 型 (单线态氧) 光氧化的作用，使用自由基清除剂深入研究光降解的机制。结果表明，单线态氧是参与 TPPS 敏化微污染物光氧化的主要 ROS。通过测量 O 的磷光寿命，研究了 MPs 与重水中 O 的相互作用。在 DO 缓冲液 (pD 7、9 和 10.8) 中测定了 MPs 对 O 的总 (物理和化学) 猝灭的速率常数 (kq)。确定了单线态氧猝灭和与 MPs 反应的速率常数，并估计了 MPs 对激发态 TPPS 的猝灭速率常数。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f775/9412460/ebe5d336fdaa/molecules-27-05260-g005a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f775/9412460/9152b275f31e/molecules-27-05260-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f775/9412460/6c71e46fc90d/molecules-27-05260-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f775/9412460/3c43c3d0dea6/molecules-27-05260-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f775/9412460/9c2b4e226282/molecules-27-05260-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f775/9412460/ebe5d336fdaa/molecules-27-05260-g005a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f775/9412460/9152b275f31e/molecules-27-05260-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f775/9412460/6c71e46fc90d/molecules-27-05260-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f775/9412460/3c43c3d0dea6/molecules-27-05260-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f775/9412460/9c2b4e226282/molecules-27-05260-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f775/9412460/ebe5d336fdaa/molecules-27-05260-g005a.jpg

相似文献

1
TPPS-Sensitized Photooxidation of Micropollutants-Singlet Molecular Oxygen Kinetic Study.基于 TPPS 的微污染物敏化光氧化—单线态氧动力学研究。
Molecules. 2022 Aug 17;27(16):5260. doi: 10.3390/molecules27165260.
2
The influence of human serum albumin on the photogeneration of singlet oxygen by meso-tetra(4-sulfonatophenyl)porphyrin. An infrared phosphorescence study.人血清白蛋白对中位-四(4-磺酸基苯基)卟啉单线态氧光生成的影响。一项红外磷光研究。
J Fluoresc. 2006 May;16(3):355-9. doi: 10.1007/s10895-005-0057-5. Epub 2006 Feb 9.
3
On the photooxidation of the multifunctional drug niclosamide. A kinetic study in the presence of vitamin B2 and visible light.关于多功能药物氯硝柳胺的光氧化作用。在维生素B2和可见光存在下的动力学研究。
Redox Rep. 2015;20(6):259-66. doi: 10.1179/1351000215Y.0000000010. Epub 2015 Apr 21.
4
Singlet oxygen-sensitized delayed fluorescence of common water-soluble photosensitizers.常见水溶性光敏剂的单线态氧敏化延迟荧光。
Photochem Photobiol Sci. 2013 Oct;12(10):1873-84. doi: 10.1039/c3pp50170a.
5
Synthesis of meso-tetra-(4-sulfonatophenyl) porphyrin (TPPS) - CuInS/ZnS quantum dots conjugate as an improved photosensitizer.介孔四（4-磺酸钠苯基）卟啉（TPPS）-CuInS/ZnS 量子点缀合物的合成作为一种改良的光敏剂。
Int J Nanomedicine. 2019 Aug 30;14:7065-7078. doi: 10.2147/IJN.S211959. eCollection 2019.
6
Effects of meso-tetrakis (4-sulfonatophenyl) porphyrin (TPPS) aggregation on its spectral and kinetic characteristics and singlet oxygen production.四(4-磺基苯基)卟啉（TPPS）聚集对其光谱和动力学特性及单线态氧产生的影响。
Spectrochim Acta A Mol Biomol Spectrosc. 2021 Nov 15;261:120063. doi: 10.1016/j.saa.2021.120063. Epub 2021 Jun 10.
7
Influence of the peptide bond on the singlet molecular oxygen-mediated (O2[1 delta g]) photooxidation of histidine and methionine dipeptides. A kinetic study.肽键对组氨酸和蛋氨酸二肽的单线态分子氧介导（O₂[¹Δg]）光氧化的影响。一项动力学研究。
Photochem Photobiol. 1993 Mar;57(3):447-52. doi: 10.1111/j.1751-1097.1993.tb02317.x.
8
Chemistry of Singlet Oxygen with a Cadmium-Sulfur Cluster: Physical Quenching versus Photooxidation.单线态氧与硫化镉簇合物的反应化学：物理猝灭与光氧化。
J Am Chem Soc. 2019 Jan 9;141(1):67-71. doi: 10.1021/jacs.8b10516. Epub 2018 Dec 27.
9
Electron spin resonance and luminescence spectroscopic observation and kinetic study of chemical and physical singlet oxygen quenching by resveratrol in methanol.电子自旋共振和发光光谱观察及动力学研究白藜芦醇在甲醇中化学和物理单重态氧猝灭。
J Agric Food Chem. 2010 Nov 24;58(22):11888-95. doi: 10.1021/jf101587c. Epub 2010 Nov 1.
10
Nanoparticles with Embedded Porphyrin Photosensitizers for Photooxidation Reactions and Continuous Oxygen Sensing.嵌入卟啉类光敏剂的纳米颗粒用于光氧化反应和连续氧传感。
ACS Appl Mater Interfaces. 2017 Oct 18;9(41):36229-36238. doi: 10.1021/acsami.7b12009. Epub 2017 Oct 4.

引用本文的文献

1
Probing mechanism of Rhodamine B decolorization under homogeneous conditions via pH-controlled photocatalysis with anionic porphyrin.通过阴离子卟啉的pH控制光催化在均相条件下罗丹明B脱色的探究机制
Sci Rep. 2024 Sep 30;14(1):22600. doi: 10.1038/s41598-024-73586-3.

本文引用的文献

1
Theoretical study on the mechanism and kinetics of the formation β-carotene epoxides from the oxidative degradation of β-carotene.β-胡萝卜素氧化降解生成β-胡萝卜素环氧化物的反应机理和动力学的理论研究。
Food Chem. 2022 Sep 30;389:133082. doi: 10.1016/j.foodchem.2022.133082. Epub 2022 Apr 26.
2
Photosensitized Dimerization of Tyrosine: The Oxygen Paradox.酪氨酸的光敏二聚化：氧悖论。
Photochem Photobiol. 2022 May;98(3):687-695. doi: 10.1111/php.13557. Epub 2021 Nov 17.
3
Effects of meso-tetrakis (4-sulfonatophenyl) porphyrin (TPPS) aggregation on its spectral and kinetic characteristics and singlet oxygen production.
四(4-磺基苯基)卟啉（TPPS）聚集对其光谱和动力学特性及单线态氧产生的影响。
Spectrochim Acta A Mol Biomol Spectrosc. 2021 Nov 15;261:120063. doi: 10.1016/j.saa.2021.120063. Epub 2021 Jun 10.
4
Mechanistic Insight into the Reactivities of Aqueous-Phase Singlet Oxygen with Organic Compounds.水中单重态氧与有机化合物反应活性的机理研究。
Environ Sci Technol. 2021 Jun 15;55(12):8054-8067. doi: 10.1021/acs.est.1c01712. Epub 2021 Jun 7.
5
Chemistry and Reaction of Singlet Oxygen in Foods.食品中单线态氧的化学性质与反应
Compr Rev Food Sci Food Saf. 2002 Jul;1(2):58-72. doi: 10.1111/j.1541-4337.2002.tb00007.x.
6
Singlet molecular oxygen by direct excitation.通过直接激发产生的单线态分子氧。
Photochem Photobiol Sci. 2008 Feb;7(2):235-9. doi: 10.1039/b714286b. Epub 2007 Nov 30.
7
Rose bengal-sensitized photooxidation of 2-chlorophenol in water using solar simulated light.使用模拟太阳光对水中的2-氯苯酚进行孟加拉玫瑰红敏化光氧化反应。
Water Res. 2005 Jan-Feb;39(2-3):412-22. doi: 10.1016/j.watres.2004.09.019.
8
Quenching of singlet molecular oxygen (1O2) by azide anion in solvent mixtures.叠氮阴离子在混合溶剂中对单线态分子氧（¹O₂）的猝灭作用。
Photochem Photobiol. 2001 Dec;74(6):760-4. doi: 10.1562/0031-8655(2001)074<0760:qosmoo>2.0.co;2.
9
Fundamental aspects of reactive oxygen species, or what's the matter with oxygen?活性氧的基本方面，或者说氧是怎么回事？
Ann N Y Acad Sci. 1999;893:13-8. doi: 10.1111/j.1749-6632.1999.tb07814.x.
10
Quenching of singlet molecular oxygen by carnosine and related antioxidants. Monitoring 1270-nm phosphorescence in aqueous media.肌肽及相关抗氧化剂对单线态分子氧的猝灭。监测水介质中的1270纳米磷光。
Biochem Mol Biol Int. 1997 Apr;41(4):687-94. doi: 10.1080/15216549700201731.