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由单壁碳纳米管/芳纶纳米纤维复合材料制成的可折叠可切割薄片的焦耳热效应。

The Joule Heating Effect of a Foldable and Cuttable Sheet Made of SWCNT/ANF Composite.

作者信息

Koo Min Ye, Lee Gyo Woo

机构信息

Division of Mechanical Design Engineering, Jeonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju 54896, Korea.

出版信息

Nanomaterials (Basel). 2022 Aug 13;12(16):2780. doi: 10.3390/nano12162780.

Abstract

A foldable and cuttable sheet heater was fabricated using single-walled carbon nanotubes (SWCNTs) and aramid nanofibers (ANFs). SWCNTs are particularly well suited for Joule heating based on their high thermal stability, electrical properties, high current density, and aspect ratio. When the SWCNT/ANF composite reaches a high temperature during Joule heating, ANFs will endure this temperature due to their impressive thermal stability, derived from aramid fibers. With the aim of achieving a synergistic effect between the SWCNTs and ANFs, 0-100 wt% SWCNT/ANF composite sheets were fabricated by tip-type sonication and vacuum filtration. After assessing the thermal stability and electrical properties of the composite sheets, the Joule heating effect was analyzed. TGA showed that our sheet had high thermal stability in an air condition up to around 500 °C. The electrical conductivity of the composite sheet was improved as the amount of SWCNT added rose to 790.0 and 747.5 S/cm in the 75 and 100_SWCNTs/ANF, respectively. The maximum heating temperature, up to 280 °C, reached by Joule heating was measured as a function of SWCNT content and input voltage, and the relationship among SWCNT content, input voltage, heating temperature, and electric power was described. Mechanical properties were also measured in a temperature range similar to the heating temperature of 300 °C reached by Joule heating. Ultimately, we obtained a foldable and cuttable composite sheet with a stretchable structure, capable of being molded into a variety of shapes. This energy-efficient material can potentially be employed in any device in which a heater is required to deliver high temperatures.

摘要

利用单壁碳纳米管(SWCNT)和芳纶纳米纤维(ANF)制备了一种可折叠、可切割的片状加热器。SWCNT因其高热稳定性、电学性能、高电流密度和长径比,特别适合焦耳加热。当SWCNT/ANF复合材料在焦耳加热过程中达到高温时,由于其源自芳纶纤维的出色热稳定性,ANF能够承受该温度。为了实现SWCNT和ANF之间的协同效应,通过尖端式超声处理和真空过滤制备了0-100 wt%的SWCNT/ANF复合片材。在评估复合片材的热稳定性和电学性能后,分析了焦耳加热效应。热重分析(TGA)表明,我们的片材在高达约500°C的空气条件下具有高热稳定性。随着添加的SWCNT量增加,复合片材的电导率分别在75_SWCNT/ANF和100_SWCNT/ANF中提高到790.0和747.5 S/cm。测量了焦耳加热达到的最高加热温度(高达280°C)与SWCNT含量和输入电压的函数关系,并描述了SWCNT含量、输入电压、加热温度和电功率之间的关系。还在与焦耳加热达到的300°C加热温度相似的温度范围内测量了机械性能。最终,我们获得了一种具有可拉伸结构的可折叠、可切割复合片材,能够被模制成各种形状。这种节能材料有可能应用于任何需要加热器提供高温的设备中。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c799/9412537/721052a17c44/nanomaterials-12-02780-g001.jpg

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