High-Sensitivity Ammonia Sensors with Carbon Nanowall Active Material via Laser-Induced Transfer.

Ammonia sensors with high sensitivity, reproducible response, and low cost are of paramount importance for medicine, i.e., being a biomarker to diagnose lung and renal conditions, and agriculture, given that fertilizer application and livestock manure account for more than 80% of NH emissions. Thus, in this work, we report the fabrication of ultra-sensitive ammonia sensors by a rapid, efficient, and solvent-free laser-based procedure, i.e., laser-induced forward transfer (LIFT). LIFT has been used to transfer carbon nanowalls (CNWs) onto flexible polyimide substrates pre-patterned with metallic electrodes. The feasibility of LIFT is validated by the excellent performance of the laser-printed CNW-based sensors in detecting different concentrations of NH in the air, at room temperature. The sensors prepared by LIFT show reversible responses to ammonia when exposed to 20 ppm, whilst at higher NH concentrations, the responses are quasi-dosimetric. Furthermore, the laser-printed CNW-based sensors have a detection limit as low as 89 ppb and a response time below 10 min for a 20 ppm exposure. In addition, the laser-printed CNW-based sensors are very robust and can withstand more than 200 bending cycles without loss of performance. This work paves the way for the application and integration of laser-based techniques in device fabrication, overcoming the challenges associated with solvent-assisted chemical functionalization.