Ding Yunpeng, Jiao Sijia, Zhang Yizhuang, Shi Zhiai, Hu Jinbiao, Wang Xulei, Li Zhiyuan, Wang Hanying, Guo Xiaoqin
School of Materials, Zhengzhou University of Aeronautics, Zhengzhou 450046, China.
Nanomaterials (Basel). 2022 Aug 21;12(16):2877. doi: 10.3390/nano12162877.
Carbon nanotube-reinforced magnesium matrix (CNTs/Mg) composite has great application potential in the transportation industry, but the trade-off between strength and ductility inhibits its widespread application. In order to balance the strength and plasticity of the composite, in this work, on the basis of the AZ61 matrix composite homogeneously reinforced by Ni-coated CNTs (hard phase), 30 vol.% large-size AZ61 particles are introduced as an isolated soft phase to fabricate hierarchical CNTs/AZ61 composites. The compression tests show the fracture strain and compressive strength of this composite increases by 54% and 8%, respectively, compared with homogeneous CNTs/AZ61 composite. During deformation, the hard phase is mainly responsible for bearing the load and bringing high strength, due to the precipitation of the MgAl phase, uniformly dispersed CNT and strong interfacial bonding of the CNTs/Mg interface through nickel plating and interfacial chemical reaction. Furthermore, the toughening of the soft phase results in high ductility. With the increase in CNT content, the compressive strength of composites is nearly unchanged but the fracture strain gradually decreases due to the stress concentration of CNT and its agglomeration.
碳纳米管增强镁基(CNTs/Mg)复合材料在交通运输行业具有巨大的应用潜力,但强度与延展性之间的权衡阻碍了其广泛应用。为了平衡复合材料的强度和塑性,在本研究中,在由镀镍碳纳米管(硬相)均匀增强的AZ61基复合材料的基础上,引入30体积%的大尺寸AZ61颗粒作为孤立的软相,以制备分级结构的CNTs/AZ61复合材料。压缩试验表明,与均匀的CNTs/AZ61复合材料相比,该复合材料的断裂应变和抗压强度分别提高了54%和8%。在变形过程中,由于MgAl相的析出、均匀分散的碳纳米管以及通过镀镍和界面化学反应实现的碳纳米管与镁界面的强界面结合,硬相主要负责承载载荷并带来高强度。此外,软相的增韧作用导致了高延展性。随着碳纳米管含量的增加,由于碳纳米管的应力集中及其团聚,复合材料的抗压强度几乎不变,但断裂应变逐渐降低。