Department of Chemistry, Education Center, Faculty of Engineering, Chiba Institute of Technology, Shibazono, Narashino, Chiba 275-0023, Japan.
J Org Chem. 2022 Sep 16;87(18):12434-12440. doi: 10.1021/acs.joc.2c01188. Epub 2022 Aug 26.
A flexible cylindrical cryptand () with two -phenylene-26-crown-8 ethers has been prepared, and its complexing properties with respect to tetravalent cationic bis-paraquat guests have been investigated. Diffusion-ordered spectroscopy nuclear magnetic resonance (NMR) and titration experiments using cold electrospray ionization mass spectrometry and H NMR revealed that has versatile complexing properties with respect to tetravalent cationic guests used despite the guest molecules' length and shape.
一种具有两个 - 亚苯基-26-冠-8 醚的柔性圆柱形cryptand（）已被制备，并研究了其与四价阳离子双对醌客体的络合性质。扩散有序光谱核磁共振（NMR）和使用冷电喷雾电离质谱和 H NMR 的滴定实验表明，尽管客体分子的长度和形状不同，但 对所用的四价阳离子客体具有多种络合性质。
