二氧化碳的活化：9-卡宾-9-硼氟苯单负离子作用下三氧化二硼酮到发光二氧杂硼烷酮的一氧化碳释放转化。
Activation of Carbon Dioxide by 9-Carbene-9-borafluorene Monoanion: Carbon Monoxide Releasing Transformation of Trioxaborinanone to Luminescent Dioxaborinanone.
机构信息
Department of Chemistry, University of Virginia, 409 McCormick Road, Charlottesville, Virginia 22904, United States.
Department of Chemistry and Physics, La Trobe Institute for Molecular Science, La Trobe University, Melbourne 3086, Victoria, Australia.
出版信息
J Am Chem Soc. 2022 Sep 14;144(36):16276-16281. doi: 10.1021/jacs.2c06845. Epub 2022 Aug 29.
The first structurally characterized example of a trioxaborinanone () is produced by the reaction of a 9-carbene-9-borafluorene monoanion and carbon dioxide. When compound is heated or irradiated with UV light, carbon monoxide (CO) is released, and a luminescent dioxaborinanone () is formed. Notably, carbon monoxide releasing molecules (CORMs) are of interest for their ability to deliver a specific amount of CO. Due to the turn-on fluorescence observed as a result of the conversion to , CORM serves as a means to optically observe CO loss "by eye" under thermal or photochemical conditions.
第一个结构特征明确的三氧杂硼烷酮（）是通过 9-卡宾-9-硼氟苯单阴离子与二氧化碳反应得到的。当化合物加热或用紫外光照射时，会释放出一氧化碳（CO），形成发光的二氧杂硼烷酮（）。值得注意的是，一氧化碳释放分子（CORM）因其能够输送特定量的 CO 而受到关注。由于观察到转化为的荧光开启，CORM 可作为在热或光化学条件下“用眼睛”光学观察 CO 损失的手段。
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