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基于氧化锆、氧化石墨烯和糊精制备不同吸附剂,用于从水溶液中去除绿色孔雀石染料。

Fabrication of different adsorbents based on zirconium oxide, graphene oxide, and dextrin for removal of green malachite dye from aqueous solutions.

机构信息

Department of Chemistry, Faculty of Science, Shahr-e-Qods Branch, Islamic Azad University, Tehran, Iran.

Department of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, Iran.

出版信息

Environ Res. 2022 Nov;214(Pt 4):114042. doi: 10.1016/j.envres.2022.114042. Epub 2022 Aug 28.

Abstract

In this study, graphene oxide and amine graphene were studied by binding to dextrin and zirconium oxide nanoparticles as adsorbent nanocomposites to the removal of dye. Identification and characterization of the synthesized materials were examined using FTIR, XRD, SEM, and BET analyses. Adsorption tests between adsorbents and green malachite (MG) dye solution for the synthesized nanocomposites were performed by considering parameters such as contact time, solution pH, and adsorbent dosage. The data indicated that dye removal increased with increasing the amount of adsorbent dosage. Increased dye removal by increasing the adsorbent dosage can be attributed to the increase of availability of the number of active sites. The active adsorption sites are saturated during the adsorption process, by the molecules of the adsorbate and filled over time. The results showed that the synthesized bio-composite had malachite green removal ability from aqueous media.

摘要

在这项研究中,通过将氧化石墨烯和胺基石墨烯与糊精和氧化锆纳米粒子结合作为吸附纳米复合材料,研究了其对染料的去除作用。使用 FTIR、XRD、SEM 和 BET 分析对合成材料进行了鉴定和表征。通过考虑接触时间、溶液 pH 值和吸附剂用量等参数,对合成纳米复合材料与绿色孔雀石(MG)染料溶液之间的吸附作用进行了测试。数据表明,随着吸附剂用量的增加,染料去除率也随之增加。增加吸附剂用量可以提高染料去除率,这归因于增加了活性位点的数量。在吸附过程中,吸附剂上的活性吸附位点会被吸附质分子饱和,随着时间的推移,这些吸附位点会逐渐填满。结果表明,所合成的生物复合材料具有从水介质中去除孔雀石绿的能力。

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