Zhao Yuliang, He Weixiang, Song Dongfu, Shen Fanghua, Li Xinxin, Sun Zhenzhong, Wang Yao, Liu Shuhong, Du Yong, Fernández Ricardo
Neutron Scattering Technical Engineering Research Centre, School of Mechanical Engineering, Dongguan University of Technology, Dongguan 523808, China; Centro Nacional de Investigaciones Metalúrgicas (CENIM), C.S.I.C., Avda. de Gregorio del Amo 8, Madrid 28040, Spain.
Neutron Scattering Technical Engineering Research Centre, School of Mechanical Engineering, Dongguan University of Technology, Dongguan 523808, China.
Ultrason Sonochem. 2022 Sep;89:106139. doi: 10.1016/j.ultsonch.2022.106139. Epub 2022 Aug 26.
Refining the α-Al grain size and controlling the morphology of intermetallic phases during solidification of Al alloys using ultrasonic melt processing (USMP) and Al-Ti-B have been extensively used in academic and industry. While, their synergy effect on the formation of these phases has not yet clearly demonstrated. In this paper, the influence of USMP and Al-Ti-B on the solidified microstructure of multicomponent Al-4.5Cu-0.5Mn-0.5Mg-0.2Si-xFe alloys (x = 0.7, and 1.2 wt%) has been comparatively studied. The results show that the USMP + Al-Ti-B method produce a more profound refinement effect than the individual methods. In addition, the area of single Fe-rich phases in both alloys with USMP + Al-Ti-B are also refined compared with conventional methods. A mechanism is proposed for the refinement, which are the deagglomerated TiB parties induced by USMP providing more effective nucleation sites for α-Al, and the refined interdendritic regions limited the growth of Fe-rich phases in the following eutectic reaction. Finally, the application of combined USMP + Al-Ti-B methods is feasible in microstructural refinement, resulting in the improving the casting soundness and mechanical properties of alloys.
利用超声熔体处理(USMP)细化铝合金凝固过程中的α-Al晶粒尺寸并控制金属间相的形态,以及Al-Ti-B,已在学术界和工业界得到广泛应用。然而,它们对这些相形成的协同效应尚未得到明确证明。本文对USMP和Al-Ti-B对多组分Al-4.5Cu-0.5Mn-0.5Mg-0.2Si-xFe合金(x = 0.7和1.2 wt%)凝固组织的影响进行了比较研究。结果表明,USMP + Al-Ti-B方法比单独使用的方法产生更显著的细化效果。此外,与传统方法相比,采用USMP + Al-Ti-B的两种合金中富Fe单相的面积也得到了细化。提出了一种细化机制,即USMP诱导的TiB团聚体解体为α-Al提供了更有效的形核位点,细化的枝晶间区域限制了后续共晶反应中富Fe相的生长。最后,USMP + Al-Ti-B组合方法在组织细化方面的应用是可行的,从而提高了合金的铸造质量和力学性能。