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用于光催化废水处理的缺陷型二氧化钛基纳米颗粒的制备及改性方法——综述

Preparation and modification methods of defective titanium dioxide-based nanoparticles for photocatalytic wastewater treatment-a comprehensive review.

作者信息

Haruna Abdurrashid, Chong Fai-Kait, Ho Yeek-Chia, Merican Zulkifli Merican Aljunid

机构信息

Department of Fundamental and Applied Sciences, Universiti Teknologi PETRONAS, 32610 Seri Iskandar, Perak Darul Ridzuan, Malaysia.

Department of Chemistry, Ahmadu Bello University, Zaria, Nigeria.

出版信息

Environ Sci Pollut Res Int. 2022 Oct;29(47):70706-70745. doi: 10.1007/s11356-022-22749-8. Epub 2022 Aug 31.

DOI:10.1007/s11356-022-22749-8
PMID:36044146
Abstract

The rapid population growth and industrial expansion worldwide have created serious water contamination concerns. To curb the pollution issue, it has become imperative to use a versatile material for the treatment. Titanium dioxide (TiO) has been recognized as the most-studied nanoparticle in various fields of science and engineering due to its availability, low cost, efficiency, and other fascinating properties with a wide range of applications in modern technology. Recent studies revealed the photocatalytic activity of the material for the treatment of industrial effluents to promote environmental sustainability. With the wide band gap energy of 3.2 eV, TiO can be activated under UV light; thus, many strategies have been proposed to extend its photoabsorption to the visible light region. In what follows, this has generated increasing attention to study its characteristics and structural modifications in different forms for photocatalytic applications. The present review provides an insight into the understanding of the synthesis methods of TiO, the current progress in the treatment techniques for the degradation of wide environmental pollutants employing modified TiO nanoparticles, and the factors affecting its photocatalytic activities. Further, recent developments in using titania for practical applications, the approach for designing novel nanomaterials, and the prospects and opportunities in this exciting area have been discussed.

摘要

全球人口的快速增长和工业扩张引发了严重的水污染问题。为了遏制污染问题,使用一种多功能材料进行处理已变得势在必行。二氧化钛(TiO)因其可用性、低成本、高效性以及在现代技术中广泛应用的其他迷人特性,已成为科学与工程各个领域研究最多的纳米粒子。最近的研究揭示了该材料在处理工业废水以促进环境可持续性方面的光催化活性。由于二氧化钛具有3.2电子伏特的宽带隙能量,它可以在紫外光下被激活;因此,人们提出了许多策略将其光吸收扩展到可见光区域。接下来,这引发了越来越多的关注,以研究其在光催化应用中不同形式的特性和结构改性。本综述深入探讨了二氧化钛的合成方法、使用改性二氧化钛纳米粒子降解广泛环境污染物的处理技术的当前进展以及影响其光催化活性的因素。此外,还讨论了二氧化钛在实际应用中的最新进展、新型纳米材料的设计方法以及这一令人兴奋领域的前景和机遇。

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