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用于光催化应用的二氧化钛纳米材料的最新进展

Recent Progress on Titanium Dioxide Nanomaterials for Photocatalytic Applications.

作者信息

Nasr Maryline, Eid Cynthia, Habchi Roland, Miele Philippe, Bechelany Mikhael

机构信息

Institut Européen des Membranes IEM, UMR-5635, Université de Montpellier, ENSCM, CNRS, Place Eugène Bataillon, F-, 34095, Montpellier Cedex 5, France.

EC2M, Faculty of Sciences 2, campus Pierre Gemayel, Fanar, Lebanese University, 90656, Lebanon.

出版信息

ChemSusChem. 2018 Sep 21;11(18):3023-3047. doi: 10.1002/cssc.201800874. Epub 2018 Aug 19.

DOI:10.1002/cssc.201800874
PMID:29984904
Abstract

Environmental and energy problems have drawn much attention owing to rapid population growth and accelerated economic development. For instance, photocatalysis, "a green technology", plays an important role in solar-energy conversion owing to its potential to solve energy and environmental problems. Recently, many efforts have been devoted to improving visible-light photocatalytic activity by using titanium dioxide as a photocatalyst as a result of its wide range of applications in the energy and environment fields. However, fast charge recombination and an absorption edge in the UV range limit the photocatalytic efficiency of TiO under visible-light irradiation. Many investigations have been undertaken to overcome the limitations of TiO and, therefore, to enhance its photocatalytic activity under visible light. The present literature review focuses on different strategies used to promote the separation efficiency of electron-hole pairs and to shift the absorption edge of TiO to the visible region. Current synthesis techniques used to elaborate several nanostructures of TiO -based materials, recent progress in enhancing visible photocatalytic activity, and different photocatalysis applications will be discussed. On the basis of the studies reported in the literature, we believe that this review will help in the development of new strategies to improve the visible-light photocatalytic performance of TiO -based materials further.

摘要

由于人口的快速增长和经济发展的加速,环境与能源问题已备受关注。例如,光催化作为一种“绿色技术”,因其在解决能源和环境问题方面的潜力,在太阳能转换中发挥着重要作用。近来,由于二氧化钛在能源和环境领域的广泛应用,人们致力于通过使用二氧化钛作为光催化剂来提高可见光光催化活性。然而,快速的电荷复合以及紫外光范围内的吸收边限制了二氧化钛在可见光照射下的光催化效率。为克服二氧化钛的这些局限性并因此提高其在可见光下的光催化活性,人们已开展了许多研究。本文献综述聚焦于用于提高电子 - 空穴对分离效率以及将二氧化钛的吸收边移至可见光区域的不同策略。将讨论用于制备几种二氧化钛基材料纳米结构的当前合成技术、提高可见光催化活性的最新进展以及不同的光催化应用。基于文献中报道的研究,我们相信本综述将有助于进一步开发新策略以改善二氧化钛基材料的可见光光催化性能。

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