Zhang Haozhe, Xiong Ting, Zhou Tianzhu, Zhang Xiao, Wang Yuntian, Zhou Xuhui, Wei Lei
School of Electrical and Electronic Engineering, Nanyang Technological University, 639798 Singapore.
ACS Appl Mater Interfaces. 2022 Sep 14;14(36):41045-41052. doi: 10.1021/acsami.2c11638. Epub 2022 Sep 1.
Multifunctional batteries have attracted increasing attention, offering additional functionalities beyond the conventional batteries. Herein, we report a fiber-shaped Zn ion battery that not only acts as a high-performance power supply but also provides a sensing function to monitor human motions. Titanium fiber coated with α-MnO nanoflowers is exploited as the cathode for the fiber-shaped Zn ion battery, taking full advantage of such unique three-dimensional nanoflower structures of α-MnO with a large electrochemically active surface area and fast electrochemical reaction kinetics. Thus, the obtained fiber-shaped Zn ion battery shows a high capacity of 280 mAh g at 0.1 A g, resulting in a notable energy density of 396 Wh kg, good stability (capacity retention of 80.6% after 300 cycles), and high flexibility. As a demonstration, an electronic watch and five LEDs are successfully driven by two fiber-shaped Zn ion batteries. Furthermore, the fiber-shaped Zn ion battery is integrated with a strain sensor based on a carbon nanotube/polydimethylsiloxane film, offering good sensitivity to monitor motions of different body parts, such as the wrist, finger, elbow, and knee. This work provides insights into multifunctional battery applications for next-generation wearable electronics.
多功能电池已引起越来越多的关注,它具有超越传统电池的附加功能。在此,我们报道了一种纤维状锌离子电池,它不仅作为高性能电源,还提供监测人体运动的传感功能。涂覆有α-MnO纳米花的钛纤维被用作纤维状锌离子电池的阴极,充分利用了α-MnO独特的三维纳米花结构,其具有大的电化学活性表面积和快速的电化学反应动力学。因此,所制备的纤维状锌离子电池在0.1 A g下显示出280 mAh g的高容量,从而具有396 Wh kg的显著能量密度、良好的稳定性(300次循环后容量保持率为80.6%)和高柔韧性。作为演示,两块纤维状锌离子电池成功驱动了一块电子手表和五个发光二极管。此外,纤维状锌离子电池与基于碳纳米管/聚二甲基硅氧烷薄膜的应变传感器集成在一起,对监测不同身体部位(如手腕、手指、肘部和膝盖)的运动具有良好的灵敏度。这项工作为下一代可穿戴电子产品的多功能电池应用提供了见解。