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改进的消费后柔性塑料机械回收工艺的质量评估和经济评估。

Quality evaluation and economic assessment of an improved mechanical recycling process for post-consumer flexible plastics.

机构信息

Laboratory for Chemical Technology (LCT), Department of Materials, Textiles and Chemical Engineering, Faculty of Engineering and Architecture, Ghent University, Ghent, Belgium; Circular Plastics, Department of Circular Chemical Engineering (CCE), Faculty of Science and Engineering, Maastricht University, Geleen, the Netherlands.

Laboratory for Circular Process Engineering (LCPE), Department of Green Chemistry and Technology, Faculty of Bioscience Engineering, Ghent University, Campus Kortrijk, Belgium.

出版信息

Waste Manag. 2022 Nov;153:41-51. doi: 10.1016/j.wasman.2022.08.018. Epub 2022 Aug 29.

Abstract

Packaging represents the largest fraction of plastic waste in Europe. Currently, mechanical recycling schemes are mainly focused on the recovery of rigid packaging (like bottles), while for flexible packaging, also called films, recycling rates remain very low. Existing mechanical recycling technologies for these films are quite basic, especially in the case of complicated post-consumer flexible plastics (PCFP) waste, leading to regranulate qualities that are often subpar for renewed use in demanding film applications. In this study, the technical and economic value of an improved mechanical recycling process (additional sorting, hot washing, and improved extrusion) of PCFPs is investigated. The quality of the four types of resulting regranulates is evaluated for film and injection molding applications. The obtained Polyethylene-rich regranulates in blown films offer more flexibility (45-60%), higher ductility (27-55%), and enhanced tensile strength (5-51%), compared to the conventional mechanical recycling process. Likewise, for injection molded samples, they exhibit more flexibility (19-49%), enhanced ductility (7 to 20 times), and higher impact strength (1.8 to 3.8 times). An economic assessment is made between the obtained increased market value and the capital investment required. It is shown that the economic value can be increased by 5-38% through this improved recycling process. Overall, the study shows that it is possible to increase the mechanical recycling quality of PCFP in an economically viable way, thus opening the way for new application routes and overall increased recycling rates.

摘要

包装占欧洲塑料废物的最大份额。目前,机械回收计划主要集中在回收刚性包装(如瓶子)上,而对于柔性包装,也称为薄膜,回收利用率仍然很低。现有的这些薄膜的机械回收技术相当基础,特别是对于复杂的消费后柔性塑料(PCFP)废物,导致再颗粒的质量通常不适合在要求苛刻的薄膜应用中重新使用。在这项研究中,研究了改进的 PCFPs 机械回收工艺(额外的分类、热清洗和改进的挤出)的技术和经济价值。评估了四种再颗粒在薄膜和注塑成型应用中的质量。与传统的机械回收工艺相比,吹塑薄膜中的富含聚乙烯的再颗粒具有更高的柔韧性(45-60%)、更高的延展性(27-55%)和增强的拉伸强度(5-51%)。同样,对于注塑成型的样品,它们表现出更高的柔韧性(19-49%)、增强的延展性(7 到 20 倍)和更高的冲击强度(1.8 到 3.8 倍)。对获得的增加的市场价值和所需的资本投资进行了经济评估。结果表明,通过这种改进的回收工艺,可以将经济价值提高 5-38%。总的来说,该研究表明,以经济可行的方式提高 PCFP 的机械回收质量是可能的,从而为新的应用途径和整体提高的回收利用率开辟了道路。

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