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纳米纤维素的植入使气凝胶的孔结构更加丰富,有利于有效去除颗粒物。

Nanocellulose implantation enriched the pore structure of aerogel for effective particulate matter removal.

机构信息

Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China; University of Chinese Academy of Sciences, Beijing 100049, China.

Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China; Shanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201204, China.

出版信息

Int J Biol Macromol. 2022 Oct 31;219:1237-1243. doi: 10.1016/j.ijbiomac.2022.08.188. Epub 2022 Sep 2.

Abstract

Particulate matter (PM) pollution poses a serious threat to public health, disposable and degradable filter materials are expected to handle the problem in the future. Here, polyvinyl alcohol (PVA)/borax/cellulose nanofibrils (CNF) aerogels were implanted on a biodegradable corrugated paper to form composite air filters for the first time via freeze-drying the coated composite hydrogels. The low content of CNF and PVA could be cross-linked by borax to form hydrogels, which enhanced its maneuverability for surface implanting on the substrate. More importantly, the addition of CNF greatly enriched the pore structure of aerogels, which provided a structural basis for PM capture. The as-prepared composite air filters exhibited excellent filtration efficiencies of 92 % and 96 % toward PM1.0 and PM3.0, respectively. Moreover, the addition of dimethylol-5,5-dimethylhydantoin endowed the filters with an antibacterial property. This work shows a new possibility for the design of degradable and functional filter materials.

摘要

颗粒物(PM)污染对公众健康构成严重威胁,预计未来可生物降解和一次性过滤材料将能够解决这个问题。在这里,聚乙烯醇(PVA)/硼砂/纤维素纳米纤维(CNF)气凝胶首次通过冷冻干燥涂覆的复合水凝胶,被植入在可生物降解的瓦楞纸上,形成复合空气过滤器。低含量的 CNF 和 PVA 可以通过硼砂交联形成水凝胶,从而提高其在基底表面植入的可操作性。更重要的是,CNF 的添加极大地丰富了气凝胶的孔结构,为 PM 捕获提供了结构基础。所制备的复合空气过滤器对 PM1.0 和 PM3.0 的过滤效率分别达到了 92%和 96%。此外,二羟甲基-5,5-二甲基海因的添加赋予了过滤器抗菌性能。这项工作为可降解和功能性过滤材料的设计展示了新的可能性。

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