Laboratory of Molecular Materials and Devices, Department of Materials Science, Fudan University, 2005 Songhu Road, Shanghai 200438, China.
Laboratory of Molecular Materials and Devices, Department of Materials Science, Fudan University, 2005 Songhu Road, Shanghai 200438, China; Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry Chinese Academy of Sciences, Beijing 100190, China.
STAR Protoc. 2022 Aug 26;3(3):101650. doi: 10.1016/j.xpro.2022.101650. eCollection 2022 Sep 16.
Syntheses using classic coupling reactions can be tedious, leading to a dearth of ambipolar semiconducting polymers. Here, we detail the rapid synthesis of balanced ambipolar polymers by using a carbon-hydrogen (C-H) activation strategy. Using this protocol, two C-H reactive hydrogenated monomers and six ambipolar polymers can be rapidly synthesized within 2 h via C-H activation and the optoelectronic properties of the resultant polymers can be characterized. We also describe the fabrication process and performance evaluation of the ambipolar polymers-based organic transistors. For complete details on the use and execution of this protocol, please refer to Shen et al. (2022).
使用经典偶联反应的合成可能很繁琐，导致缺少双极性半导体聚合物。在这里，我们详细介绍了使用碳-氢键（C-H）活化策略快速合成平衡双极性聚合物的方法。使用该方案，通过 C-H 活化，可以在 2 小时内快速合成两种 C-H 反应性氢化单体和六种双极性聚合物，并可以对所得聚合物的光电性能进行表征。我们还描述了基于双极性聚合物的有机晶体管的制造工艺和性能评估。有关该方案使用和执行的完整详细信息，请参阅 Shen 等人（2022 年）。
