Bicalho Hudson A, Saraci Felix, Velazquez-Garcia Jose de J, Titi Hatem M, Howarth Ashlee J
Department of Chemistry and Biochemistry, Concordia University, 7141 Sherbrooke Street W., Montreal, QC, H4B 1R6, Canada.
Photo Science - Structural Dynamics in Chemical Systems, Deutsches Elektronen-Synchrotron DESY, Notkestraße 85, Hamburg, 22607, Germany.
Chem Commun (Camb). 2022 Sep 29;58(78):10925-10928. doi: 10.1039/d2cc03575h.
Y-CU-45, an analogue of Zr-MOF-808, is synthesized for the first time. Several reaction conditions are tested demonstrating that two fluorinated modulators are required for a reproducible synthesis yielding high quality material. Y-CU-45 shows high crystallinity and surface area, shining light on the potential for rare-earth cluster-based MOFs with open metal sites.
首次合成了Zr-MOF-808的类似物Y-CU-45。测试了几种反应条件，结果表明，要实现可重复合成并获得高质量材料，需要两种氟化调节剂。Y-CU-45具有高结晶度和高表面积，这为具有开放金属位点的稀土簇基金属有机框架的潜力提供了线索。
