Kedia Moon, Shankar Bhaskaran, Sathiyendiran Malaichamy
School of Chemistry, University of Hyderabad, Hyderabad 500 046, India.
Department of Chemistry, Thiagarajar College of Engineering, Madurai 625 015, India.
Inorg Chem. 2022 Sep 19;61(37):14506-14510. doi: 10.1021/acs.inorgchem.2c02408. Epub 2022 Sep 6.
Neutral heteroleptic trinuclear coordination cages containing a preorganized well-defined small spherical endocavity, which is made up of electron-deficient bowl frameworks, three coordination-induced neutral polar C-H donors, and a phenyl motif, were self-assembled via a one-pot approach; the endocavity accommodates fluoride selectively in the presence of other halides.
通过一锅法自组装得到了中性杂配三核配位笼，其包含一个预先组织好的、定义明确的小型球形内腔，该内腔由缺电子碗状骨架、三个配位诱导的中性极性C-H供体和一个苯基组成；在内腔中，氟化物能在其他卤化物存在的情况下选择性地被容纳。
