Loring Roger F
Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853, United States.
J Phys Chem A. 2022 Sep 15;126(36):6309-6313. doi: 10.1021/acs.jpca.2c04428. Epub 2022 Sep 6.
Electric force microscopy, in which a charged probe moves above a surface, can measure thermally generated electric field fluctuations from the sample. Noncontact friction measurements of energy loss from the probe have been performed over insulators, semiconductors, and conductors and have been interpreted in terms of the dielectric response of the sample. Noncontact friction over metal surfaces has recently been ascribed to dielectric relaxation of adsorbed molecules, motivating the examination of the baseline noncontact friction over a bare metal surface. The noncontact friction for a thin conducting film is calculated for a wavevector-dependent dielectric function, complementing previous calculations for insulators and semiconductors employing a dielectric continuum representation. Inclusion of the wavevector dependence in the dielectric response of a conductor enhances the friction and alters its dependence on tip-sample separation, relative to the continuum treatment.
在静电力显微镜中,带电探针在表面上方移动,它能够测量来自样品的热产生电场波动。已经在绝缘体、半导体和导体上进行了关于探针能量损失的非接触摩擦测量,并根据样品的介电响应进行了解释。最近,金属表面的非接触摩擦被归因于吸附分子的介电弛豫,这促使人们研究裸金属表面的基线非接触摩擦。对于依赖于波矢的介电函数,计算了薄导电膜的非接触摩擦,补充了先前采用介电连续体表示法对绝缘体和半导体的计算。相对于连续体处理,在导体的介电响应中包含波矢依赖性会增强摩擦并改变其对针尖 - 样品间距的依赖性。