A luminescent Eu@SOF film fabricated by electrophoretic deposition as ultrasensitive platform for styrene gas quantitative monitoring through fluorescence sensing and ANNs model.

Styrene is a harmful gas widely existing in the air, which can damage human organs. Therefore, it is very crucial to develop a sensitive, portable and simple sensor for monitoring styrene. Herein, we design and fabricate a luminescent Eu@TMA-ME/FTO film (F) through EPD method. F emits bright red light of Eu(III) ions and shows superior fluorescence response to styrene gas as a sensor, which enable real-time and quantitative monitoring for styrene gas. More importantly, F exhibits a linear response to styrene gas in a wide concentration range of 10 to 10 M and a low DL with 0.20 ppm. The efficient PET process to styrene induced by ME and the competitive absorption between styrene and F are responsible for the sensing mechanism. Besides, the detection of styrene solution is also investigated in deionized water, tap water and river water. For the further application, an intelligent ANNs model has been constructed to process the fluorescence sensing results, which can convert fluorescence sensing images to the concentration of styrene gas. The data demonstrates that ANNs model can accurately monitor the concentration of styrene gas via deep ML without tedious data processing.