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4'-氨基-3',5'-二氰基-2,2''-二氧代二螺[吲哚啉-3,1'-环戊烷-2',3''-吲哚啉]-3'-烯-5'-羧亚胺甲酯与一种未知溶剂的晶体结构和 Hirshfeld 表面分析

Crystal structure and Hirshfeld surface analysis of methyl 4'-amino-3',5'-di-cyano-2,2''-dioxodi-spiro[indoline-3,1'-cyclo-pentane-2',3''-indolin]-3'-ene-5'-carboximidate with an unknown solvent.

作者信息

Naghiyev Farid N, Khrustalev Victor N, Fortalnova Elena A, Akkurt Mehmet, Khalilov Ali N, Bhattarai Ajaya, Mamedov İbrahim G

机构信息

Department of Chemistry, Baku State University, Z. Khalilov str. 23, Az, 1148 Baku, Azerbaijan.

Peoples' Friendship University of Russia (RUDN University), Miklukho-Maklay St. 6, Moscow, 117198, Russian Federation.

出版信息

Acta Crystallogr E Crystallogr Commun. 2022 May 24;78(Pt 6):665-668. doi: 10.1107/S2056989022005370. eCollection 2022 Jun 1.

Abstract

In the title compound, CHNO, the central five-membered cyclo-pentene ring adopts an envelope conformation while the five-membered spiro 2,3-di-hydro-1-pyrrole rings exhibit twisted envelope and envelope conformations. One of the 1,3-di-hydro-2-indol-2-one units is in an axial position and the other is in a bis-ectional position. The methyl methanimidate unit is in an equatorial position. The crystal structure of the title compound is consolidated by inter-molecular N-H⋯N, N-H⋯O and C-H⋯O hydrogen bonds, forming a three dimensional network.

摘要

在标题化合物CHNO中,中心的五元环戊烯环呈信封式构象,而五元螺环2,3-二氢-1-吡咯环呈现扭曲信封式和信封式构象。1,3-二氢-2-吲哚-2-酮单元中的一个处于轴向位置,另一个处于平分位置。甲基亚氨基甲酸酯单元处于赤道位置。标题化合物的晶体结构通过分子间的N-H⋯N、N-H⋯O和C-H⋯O氢键得以巩固,形成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cea3/9431790/30996963dde9/e-78-00665-fig1.jpg

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