1-[8-苯基-9-(苯基乙炔基)-4-苯并[]咔唑-4-基]乙-1-酮的晶体结构与荧光
Crystal structure and fluorescence of 1-[8-phenyl-9-(phenyl-ethyn-yl)-4-benzo[]carbazol-4-yl]ethan-1-one.
作者信息
Hsiao Huan-Chang, Chen Pei-Lin, Chuang Shih-Ching
机构信息
Department of Applied Chemistry, National Yang Ming Chiao Tung University, Hsinchu 300093, Taiwan.
Department of Chemistry, National Tsing Hua University, Hsinchu 300044, Taiwan.
出版信息
Acta Crystallogr E Crystallogr Commun. 2022 May 13;78(Pt 6):590-593. doi: 10.1107/S2056989022004509. eCollection 2022 Jun 1.
The crystal of the title compound, CHNO, which crystallizes in the monoclinic space group 2/, was obtained by thermal evaporation of a 1:1 di-chloro-methane and hexa-nes solution of the pure compound. The crystal structure is stabilized by π-π inter-actions between benzo[]carbazole moieties and carbon-yl-carbonyl inter-actions between the two acetyl groups.
标题化合物CHNO的晶体，其结晶于单斜空间群2/，是通过对该纯化合物的二氯甲烷和己烷1:1混合溶液进行热蒸发得到的。晶体结构通过苯并[]咔唑部分之间的π-π相互作用以及两个乙酰基之间的羰基-羰基相互作用得以稳定。
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